**Abstract**

Most of the previous were regarding characteristics of sludge from urban/ municipal activities concerning environmental issues on industrial sludge discharges causing fatal disasters in the lakes and water streams. The washing treatment of mud was searched. This research study concentrated over oxidative heavy metal dissolution and sterilization washing of muddy sludge of chemical, steel and copper refinery plants. The hazardous Hg and Pd contents using washing dissolution provided recovery of metals and treated sludge as the feedstock for digestion process. The research used hazardous sludge which is the by-product of the heat treated steel manufacturing process of CN baths and sludge from pulp washing industries. However, there is a sterilization washing by microwave radiation was reported on various sludge metal contamination characteristics in wastewater treatment stage. The results of a limited number of bench-scale sludge washing experiments conducted in the tube reactor study confirmed high radiation trends for washing dissolution with H2O2 in soil samples obtained from different locations in the north lake area of discharge of at the Plant Site. In general the contaminants in waste pond soils partitioned preferentially to the fine fraction of the soil (<150 μm however, the sand fraction (0,5 mm + 150 μm) still contained significant contamination. These tests also showed that the heavy metal contaminants were highly dissolved at 45–76% in the wash water, which will reduce washing toxicity and improve metal recovers.

**Keywords:** fly ash, microwave radiation, salt slurries, metal sorption, energy toxic risk assessment, stochastic cost estimation, treatmen sorbent simulation, hybrid sorbent, waste sludge, salt slurries, Microwave activation waste water treatment, heavy metal, fly ash composts, shale
