**Abstract**

This chapter means to explain the tribological behavior of polymer-based materials, to support a beneficial introducing of those materials in actual applications based on test campaigns and their results. Generally, the designers have to take into consideration a set of tribological parameters, not only one, including friction coefficient, wear, temperature in contact, contact durability related to application. Adding materials in polymers could improve especially wear with more than one order of magnitude, but when harder fillers are added (as glass beads, short fibers, minerals) the friction coefficient is slightly increased as compared to neat polymer. In this chapter, there are presented several research studies done by the authors, from which there is point out the importance of composite formulation based on experimental results. For instance, for PBT sliding on steel there was obtained a friction coefficient between 0.15 and 0.3, but for the composite with PBT + micro glass beads, the value of friction coefficient was greater. Adding a polymer playing the role of a solid lubricant (PTFE) in these composites and also only in PBT, decreased the friction coefficient till a maximum value of 0.25. The wear parameter, linear wear rate of the block (from block-on-ring tester) was reduced from 4.5 μm/ (Nkm) till bellow 1 μm/(Nkm) for a dry sliding regime of 2.5 … 5 N, for all tested sliding velocities, for the composite PBT + 10% glass beads +10% PTFE, the most promising composite from this family of materials. This study emphasis the importance of polymer composite recipe and the test parameters. Also there are presented failure mechanisms within the tribolayer of polymer-based materials and their counterparts.

**Keywords:** polymer, composites with polymer matrix, polymer blends, tribology, wear, friction, tribolayer, tribological behavior, wear mechanisms
