**Chapter 6**

photosynthesis. Chemical Society Reviews. 2014;**43**:7501-7519

*Photophysics, Photochemical and Substitution Reactions - Recent Advances*

during light-driven H2 production. Inorganic Chemistry. 2012;**51**:2115-2120

electrocatalytic hydrogen evolution and hydrogen oxidation. Journal of the American Chemical Society. 2016;**138**:

[73] Stubbert BD, Peters JC, Gray HB. Journal of the American Chemical Society. 2011;**133**:18070-18073

Grapperhaus CA. Metal-assisted ligand centered electrocatalytic hydrogen evolution upon reduction of a bis (thiosemicarbazonato)Cu(II) complex.

[75] Zhang P, Wang M, Yang Y, Yao T, Sun L. A molecular copper catalyst for electrochemical water reduction with a large hydrogen-generation rate constant in aqueous solution. Angewandte Chemie, International Edition. 2014;

[76] Wang J, Li C, Zhou Q, Wang W, Hou Y, Zhang B, et al. Photocatalytic

complexes. Dalton Transactions. 2016;

[77] Das A, Han Z, Brennessel WW, Holland PL, Eisenberg R. Nickel complexes for robust light-driven and electrocatalytic hydrogen production from water. ACS Catalysis. 2015;**5**:

hydrogen evolution by Cu(II)

[72] Haddad AZ, Garabato BD, Kozlowski PM, Buchanan RM, Grapperhaus CA. Beyond metalhydrides: Non-transition-metal and

metal-free ligand-centered

[74] Haddad AZ, Cronin SP, Mashuta MS, Buchanan RM,

Inorganic Chemistry. 2017;**56**:

7844-7847

11254-11265

**53**(50):13806-13807

**45**:5439-5443

1397-1406

[65] Yoshida M, Ueno S, Okano Y, Usui A, Kobayashi A, Kato M. Photochemical hydrogen production from 3d transition-metal complexes bearing *o*-phenylenediamine ligands. Journal of Photochemistry and Photobiology A: Chemistry. 2015;**313**:

[66] Konno Y, Matsushita N. pHdependent color-change behavior of bis (*o*-phenylenediamine) platinum(II) complex and pH-dependent redox of bis (*o*-semibenzoquinonediimine)platinum (II) complex. Chemical Society of Japan.

[67] Matsumoto T, Chang HC, Wakizaka M, Ueno S, Kobayashi A, Nakayama A, et al. Nonpreciousmetal-assisted photochemical hydrogen

Phenylenediamine J. American Chemical Society. 2013;**135**:8646-8654

[68] Roberts GM, Williams CA, Young JD, Ullrich S, Paterson MJ, Stavros VG. Unraveling ultrafast dynamics in photoexcited aniline. Journal of the American Chemical Society. 2012;**134**:12578-12589

[69] Keffer N, Chavarot-Kerlidou M, Artero V. Hydrogen evolution catalyzed by cobaltdiimine-dioxime complexes Acc. Chemistry Research. 2015;**48**:

[70] Giorgetti M, Berrettoni M, Ascone I, Zamponi S, Seeber R, Marassi R. X-ray absorption spectroscopy study on the electrochemical reduction of Co((DO) (DOH) pn)Br2. Electrochimica Acta.

[71] Zhang P, Jacques PA, Chavarot-Kerlidou M, Wang M, Sun L, Fontecave M, et al. Phosphine coordination to a cobalt diimine– dioxime catalyst increases stability

2006;**79**:1046-1053

production from *ortho*-

1286-1295

**116**

2000;**45**:4475-4482

99-106
