**Abstract**

Polyimide has been widely used as insulating and structural materials in spacecraft due to its excellent electrical, thermal and mechanical properties. However, its charging and discharging problem in harsh space environment has been a major limit to the development of high-voltage and high-power spacecraft. In this chapter, charging and discharging phenomena of dielectric materials under electron irradiation environment were presented. First, the electrical properties of polyimide consisting of dielectric properties, trap properties, conductivity and electrical breakdown properties were investigated, which have great influences on charging and discharging characteristics. Then, a surface charging model under relatively low-energy electron irradiation was proposed for polyimide, based on the synergistic effects of electron movement above surface and charge transport in surface layer. The DC surface flashover of polyimide under electron irradiation with different energies, fluxes and incident angles was investigated. Furthermore, a deep charging model under high-energy electron irradiation with the Fluence Model for Internal Charging (FLUMIC) spectrum was established. The effects of electron flux enhancement and operating voltage on charging characteristics were discussed in different grounding modes. It indicates that the processes of discharging under electron irradiation have a close link with the charge transport characteristics of polyimide.

**Keywords:** charging and discharging, charge transport, electron irradiation, high voltage, polyimide
