**Acknowledgements**

The authors would like to thank Lic. María S. Lassa (MEByM-CONICET) for providing technical assistance in SEM imaging and EDS analysis and to Mr. Daniel E. Dueñas (CONICET, CCT-Mendoza) for high quality editing service. We are also grateful to Ing. Ramiro Oviedo Bustos (CUME SRL) and Ing. Mauro Mortarini (Ojos del Salado SRL) for contributing to our research, as well as to Ing. Mariano A. Bernardo (NIDERA SA) for providing standard seed material for bioassays. This work was supported by grant PIP No. 11220130100382CO from the National Scientific and Technical Research Council, Argentina (CONICET).
