**The Study on the Influence of Diesel Fuel Oxygenates on Exhaust Emissions**

### Miłosław Kozak

Additional information is available at the end of the chapter

http://dx.doi.org/10.5772/62005

### **Abstract**

The study discusses the use of oxygenated fuels in reduction of exhaust emissions from diesel engines. The study analyzes the physicochemical properties of oxygenated com‐ pounds in diesel fuels based on which 12 such compounds were selected for experimen‐ tal research (glycol ethers, maleates, carbonates and alcohols). The study presents the results of investigations of the influence of oxygenated fuels on the exhaust emissions un‐ der dynamic homologation cycle chassis dynamometer conditions (diesel passenger vehi‐ cle, NEDC and FTP-75 cycles). The relationship among the content of individual oxygenated compounds, the conditions of the tests cycle and the exhaust emissions has been ascertained. The performed studies and experimental research have shown that the application of oxygenated fuels in diesel engines results in a significant reduction of the PM emission at a small increase in the emission of NOx. Changes in the emission of CO and HC depend not only on the oxygen content in the fuel but also on the self-ignition quality of the applied oxygenated compounds. The application of oxygenated fuels does not influence the emission of CO2. Out of the analyzed oxygenated compounds, the most advantageous emission changes (reduction of the emission of PM, CO and HC at a small increase in the emission of NOx) are generated by the compounds of the glycol ethers group.

**Keywords:** Diesel engine, diesel fuel, oxygenates, exhaust emissions

### **1. Introduction**

An efficient transport system is one of the basic elements of every developed economy in the world. Transport is also a very important aspect of life for a large part of humanity, because it facilitates the daily movement of people. Access to transport is one of the main factors affecting the quality of life. In addition to the major benefits of transportation, there are also the adverse consequences, particularly pollution.

© 2016 The Author(s). Licensee InTech. This chapter is distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Vehicles are a major source of air pollution in developed countries, including the European Union (EU) (Fig. 1a). It should be noted that in the past 20 years, the carbon monoxide (CO) and hydrocarbons (HC) emissions from transport have decreased significantly, while NO*<sup>x</sup>* emissions, and in particular particulate matter (PM), have declined only slightly (Fig. 1b).

**Figure 1.** The share of transport in total emissions of major air pollutants in the European Union in 2009 (a) and change in emissions of these pollutants in the transport sector in 1990–2010 (b) [1]

The main sources of CO and HC emissions from transport are vehicles powered by gasoline engines. The share of vehicles with spark ignition (SI) and compression ignition (CI) engines in NO*x* emissions is similar, while vehicles with diesel engines are responsible for the majority of PM emissions. Particulate matter is among the most harmful of emissions from motor vehicles. In the report of the US Environmental Protection Agency on the dangers of exhaust gases of diesel engines [2], it has been demonstrated, on the basis of several dozen independent medical studies on humans and laboratory tests on animals, that airborne PM have carcino‐ genic effects and contribute in particular to the occurrence of lung cancers.

One of the reasons of the mentioned small reduction in PM emissions compared to other exhaust compounds is an increase in the number of sources of PM emissions, which means the number of vehicles powered by diesel engines is higher. From the middle of the past decade, more cars with diesel engines than SI were sold in the European Union. In 2012, the share of passenger vehicles with diesel engines among new cars was 56% [3]. The economic development of the countries in the European Union leads to an increase in the number of heavy vehicles, which typically use only diesel engines. This situation is well illustrated by the trends in demand for motor fuel. In 2000, the European Union had a similar demand for automotive gasoline and diesel fuels. At present, the demand for diesel fuel is twice that of gasoline, and taking into account the off-road oil consumption, it is nearly three times higher (Fig. 2). A similar situation also exists in Poland, but in this country, it is largely the result of popularity of liquefied petroleum gas (LPG). According to data from the Central Statistical Office [4], 3 925 thousand tons of gasoline and 12 219 thousand tons of diesel fuel have been sold in Poland in 2011. One of the reasons of the mentioned small reduction in PM emissions compared to other exhaust compounds is an increase in the number of sources of PM emissions, which means the number of vehicles powered by diesel engines is higher. From the middle of the past decade, more cars with diesel engines than SI were sold in the European Union. In 2012, the share of passenger vehicles with diesel engines among new cars was 56% [3]. The economic development of the countries in the European Union leads to an increase in the number of heavy vehicles, which typically use only diesel engines. This situation is well illustrated by the trends in demand for motor fuel. In 2000, the European Union had a similar demand for automotive gasoline and diesel fuels. At present, the demand for diesel fuel is twice that of gasoline, and taking into account the off-road oil consumption, it is nearly three times higher (Fig. 2). A similar situation also exists in Poland, but in this country, it is largely the result of popularity of liquefied petroleum gas (LPG). According to data from the Central Statistical Office [4], 3 925 thousand tons of gasoline and 12 219 thousand tons of diesel fuel have been sold in Poland in 2011.

**Figure 2.** Daily consumption of motor fuels in the European Union [5]

Vehicles are a major source of air pollution in developed countries, including the European Union (EU) (Fig. 1a). It should be noted that in the past 20 years, the carbon monoxide (CO) and hydrocarbons (HC) emissions from transport have decreased significantly, while NO*<sup>x</sup>* emissions, and in particular particulate matter (PM), have declined only slightly (Fig. 1b).

CO HC NOx PM

(a)

1990 1995 2000 2005 2010 Year

(b)

**Figure 1.** The share of transport in total emissions of major air pollutants in the European Union in 2009 (a) and change

The main sources of CO and HC emissions from transport are vehicles powered by gasoline engines. The share of vehicles with spark ignition (SI) and compression ignition (CI) engines in NO*x* emissions is similar, while vehicles with diesel engines are responsible for the majority of PM emissions. Particulate matter is among the most harmful of emissions from motor vehicles. In the report of the US Environmental Protection Agency on the dangers of exhaust gases of diesel engines [2], it has been demonstrated, on the basis of several dozen independent medical studies on humans and laboratory tests on animals, that airborne PM have carcino‐

genic effects and contribute in particular to the occurrence of lung cancers.

> CO HC

NOx PM

in emissions of these pollutants in the transport sector in 1990–2010 (b) [1]

The share of transport in

42 Alternative Fuels, Technical and Environmental Conditions

40

20

0

60

Change in emissions [%]

80

100

120

total emissions [%]

Figure 2. Daily consumption of motor fuels in the European Union [5] The second reason for the similar level of PM emissions from transport sources continued over the years is lower PM emission reduction efficiency of vehicles compared to the gaseous components of the exhaust. Currently, getting The second reason for the similar level of PM emissions from transport sources continued over the years is lower PM emission reduction efficiency of vehicles compared to the gaseous components of the exhaust. Currently, getting acceptably low exhaust emissions from diesel engines requires numerous and varied measures, covering at least [6]:

acceptably low exhaust emissions from diesel engines requires numerous and varied measures, covering at least [6]: **•** the optimization of the combustion process in the engine,

exhaust gas recirculation (EGR)),





The basis for the development of eco-friendly motor fuels are research programs concerning the impact of fuel on emissions of toxic components, performance, durability, and other indicators for internal combustion engines. The first such program was AQIRP (Auto/Oil Air Quality Improvement Research Program) conducted in the US in 1989–1997. However, it only researched fuels for SI engines [7]. Evaluation of the impact of fuel emissions was also one of the elements of the JCAP program (Japan Clear Air Program) implemented in Japan in 1996–2001 [8]. In the years 1993–1996, the European Union conducted its EPEFE program (European Programme on Emissions, Fuels and Engine Technologies), usually abbreviated to Auto-Oil program [9]. On the basis of research [10], it was found that the greatest impact on the level of harmful exhaust emissions from diesel engines have the following parameters of diesel fuel (Fig.



3):




The basis for the development of eco-friendly motor fuels are research programs concerning the impact of fuel on emissions of toxic components, performance, durability, and other indicators for internal combustion engines. The first such program was AQIRP (Auto/Oil Air Quality Improvement Research Program) conducted in the US in 1989–1997. However, it only researched fuels for SI engines [7]. Evaluation of the impact of fuel emissions was also one of the elements of the JCAP program (Japan Clear Air Program) implemented in Japan in 1996– 2001 [8]. In the years 1993–1996, the European Union conducted its EPEFE program (European Programme on Emissions, Fuels and Engine Technologies), usually abbreviated to Auto-Oil program [9]. On the basis of research [10], it was found that the greatest impact on the level of harmful exhaust emissions from diesel engines have the following parameters of diesel fuel (Fig. 3):



**Table 1.** Specifications of diesel fuel according to the European Directive 98/70/EC

Auto-Oil program was the only program so far that so comprehensively encompassed the issues of the impact of fuel emissions of harmful exhaust compounds. The results of the Auto-Oil program were the basis for establishing the fuel specifications of the European Union, in force since 2000, contained in the European Directive 98/70/EC. The new requirements introduced by this directive significantly changed the parameters of diesel fuels affecting the level of exhaust emissions (Table 1). Through this, the potential of conventional diesel fuels in The Study on the Influence of Diesel Fuel Oxygenates on Exhaust Emissions http://dx.doi.org/10.5772/62005 45

**•** utilization of onboard diagnostics (OBD) to monitor the emission levels of harmful com‐

The basis for the development of eco-friendly motor fuels are research programs concerning the impact of fuel on emissions of toxic components, performance, durability, and other indicators for internal combustion engines. The first such program was AQIRP (Auto/Oil Air Quality Improvement Research Program) conducted in the US in 1989–1997. However, it only researched fuels for SI engines [7]. Evaluation of the impact of fuel emissions was also one of the elements of the JCAP program (Japan Clear Air Program) implemented in Japan in 1996– 2001 [8]. In the years 1993–1996, the European Union conducted its EPEFE program (European Programme on Emissions, Fuels and Engine Technologies), usually abbreviated to Auto-Oil program [9]. On the basis of research [10], it was found that the greatest impact on the level of harmful exhaust emissions from diesel engines have the following parameters of diesel fuel

**•** fractional composition, particularly the amount of heavy hydrocarbons characterized by the

**Parameter Unit Since 2000 Since 2005** Cetane number, min. – 51 51 Sulfur content, max. ppm 350 50/101) PAH content, max. % (m/m) 11 11 Density at 15°C, max. kg/m3 845 845 Distillation, T95 max. °C 360 360

Auto-Oil program was the only program so far that so comprehensively encompassed the issues of the impact of fuel emissions of harmful exhaust compounds. The results of the Auto-Oil program were the basis for establishing the fuel specifications of the European Union, in force since 2000, contained in the European Directive 98/70/EC. The new requirements introduced by this directive significantly changed the parameters of diesel fuels affecting the level of exhaust emissions (Table 1). Through this, the potential of conventional diesel fuels in

**•** improving the fuel composition to reduce the creation of harmful exhaust compounds.

pounds by the vehicle,

44 Alternative Fuels, Technical and Environmental Conditions

(Fig. 3):

**•** density,

**•** cetane number,

**•** sulfur content.

1) 10 ppm since 2009

**•** polycyclic aromatic hydrocarbons (PAH) content,

**Table 1.** Specifications of diesel fuel according to the European Directive 98/70/EC

T90, T95, and FBP temperatures,

4 **Figure 3.** Effect of diesel fuel parameters on the exhaust emissions of the European LDD and HDD engines according to the Auto-Oil program [10]

reducing emissions was largely used up, so that further modification of the conventional fuel parameters is possible only to a limited extent. The sulfur content in fuels produced today is nearly zero, and the PAH content has been reduced to about 2–3%. Excessive increase in cetane number would have an adverse impact on the process of combustion and emissions. A further change of composition in the direction of lighter fractions is also unjustified. So to even further exploit the potential of fuels to reduce exhaust emissions of diesel engines, unconventional modifications of their properties are necessary. It seems that one of the promising fields of this type of activity is the use of oxygenated fuels, namely the introduction of components that act as carriers of oxygen (oxygenates) into the composition of diesel fuels. Oxygenated fuels are successfully utilized in SI engines to provide lower emissions of CO and HC. Due to the nature of combustion in the diesel engine, namely an inhomogeneous air–fuel mixture and local oxygen deficiency regions, the emission benefits associated with the use of oxygenated fuels in diesel engines should be even greater. This chapter is dedicated to the issue of the impact of oxygenated fuels on exhaust emissions from diesel engines.

It should be noted that the introduction of low-emission diesel fuels involves a number of potential benefits, which cannot be provided by other solutions for reducing emissions. First of all, eco-friendly fuels immediately impact the whole fleet of vehicles, and their introduction into the market in sufficient quantities (as opposed to alternative fuels) can be done in a short time. Although the unit emission reduction is probably less than one achieved with modern engine technology or alternative fuels, because of the huge scale of fuel consumption, a quick global effect may be larger than what can be achieved by several other means. In addition, low-emission fuels can provide a reduction in emissions from older vehicles, which on the one hand are the largest source of harmful exhaust emissions, and on the other hand, reducing their harmfulness is technically impossible or not cost-effective through other means. Another advantage of the low-emission diesel fuels is their impact on reducing harmful exhaust emissions in circumstances when other measures are not effective (e.g. engine start-up and warm-up period).

## **2. Requirements for oxygenated compounds used as components of diesel fuels**

Oxygen compounds used as components of oxygenated fuels must demonstrate properties that are required for all components of motor fuels. Not all oxygenates are suitable for use as an additive to diesel fuel. According to Murphy [11], potential oxygenated components must meet the following requirements:


**•** oxygenated compounds should not have a too high volatility nor too low flash point.

Additional important requirements for potential oxygenates of diesel fuels should include:


nearly zero, and the PAH content has been reduced to about 2–3%. Excessive increase in cetane number would have an adverse impact on the process of combustion and emissions. A further change of composition in the direction of lighter fractions is also unjustified. So to even further exploit the potential of fuels to reduce exhaust emissions of diesel engines, unconventional modifications of their properties are necessary. It seems that one of the promising fields of this type of activity is the use of oxygenated fuels, namely the introduction of components that act as carriers of oxygen (oxygenates) into the composition of diesel fuels. Oxygenated fuels are successfully utilized in SI engines to provide lower emissions of CO and HC. Due to the nature of combustion in the diesel engine, namely an inhomogeneous air–fuel mixture and local oxygen deficiency regions, the emission benefits associated with the use of oxygenated fuels in diesel engines should be even greater. This chapter is dedicated to the issue of the impact

It should be noted that the introduction of low-emission diesel fuels involves a number of potential benefits, which cannot be provided by other solutions for reducing emissions. First of all, eco-friendly fuels immediately impact the whole fleet of vehicles, and their introduction into the market in sufficient quantities (as opposed to alternative fuels) can be done in a short time. Although the unit emission reduction is probably less than one achieved with modern engine technology or alternative fuels, because of the huge scale of fuel consumption, a quick global effect may be larger than what can be achieved by several other means. In addition, low-emission fuels can provide a reduction in emissions from older vehicles, which on the one hand are the largest source of harmful exhaust emissions, and on the other hand, reducing their harmfulness is technically impossible or not cost-effective through other means. Another advantage of the low-emission diesel fuels is their impact on reducing harmful exhaust emissions in circumstances when other measures are not effective (e.g. engine start-up and

**2. Requirements for oxygenated compounds used as components of diesel**

Oxygen compounds used as components of oxygenated fuels must demonstrate properties that are required for all components of motor fuels. Not all oxygenates are suitable for use as an additive to diesel fuel. According to Murphy [11], potential oxygenated components must

**•** low-temperature parameters of diesel fuel and oxygenated compounds mixtures must be

**•** mixtures of diesel fuel and oxygenated compounds should not be susceptible to stratifica‐

**•** be able to mix with diesel fuel in the whole range of engine operating temperatures,

**•** oxygenated compounds should have a sufficiently high cetane number,

of oxygenated fuels on exhaust emissions from diesel engines.

46 Alternative Fuels, Technical and Environmental Conditions

warm-up period).

meet the following requirements:

suitable for the climate where they will be used,

tion as a result of contamination with water,

**fuels**

It should be noted that the fulfillment of these criteria will often depend on the amount of oxygenated compound added to the fuel composition.

The literature provides various proposals for chemical compounds to be used as oxygen compounds in fuels. Particularly, one paper [12] presents an analysis of the physicochemical properties of 71 potential oxygenated compounds. After initial selection on the basis of three parameters, such as oxygen content, density, and flashpoint temperature, 42 oxygenated compounds were addressed for further analysis, where they have been evaluated in terms of miscibility with diesel fuel and water tolerance. Seventeen compounds that at this stage rated positively were then tested for corrosive properties. Their toxicological properties, biodegrad‐ ability, and impact on elastomers were also evaluated. Based on the analyses performed, eight most promising oxygenated compounds were chosen for further use in diesel fuels: tripropy‐ lene glycol monomethyl ether, 1-methoxy-2-propanol, dipropylene glycol monomethyl ether, 2-ethoxy ethyl acetate, 2-ethoxy ethyl ether, diethyl adipate, tributyrin, and dibutyl maleate.

Bertoli and Boulouchos [13] describe the analysis of 27 prospective oxygen compounds in terms of their compatibility with diesel fuel, their oxygen content, and calorific value. This analysis found that the best oxygenated compounds are diethylene glycol dimethyl ether, diethylene glycol diethyl ether, dibutoxymethane (butylal), and dipenthylether. Delfort et al. [14] show the applicability as fuel components of 18 oxygen compounds of chemical groups such as ethers, acetals, polyacetals, and carbonates. Murphy in his works [15, 16] pointed out the inappropriate fire safety and toxicology performance of some of oxygen compounds.

## **3. Analysis of exhaust emissions from a passenger car fueled with oxygenated fuels**

### **3.1. The essence of application of oxygenated diesel fuels**

Fuel, as the integral element of combustion in the engine, has an immense effect on the composition and harmfulness of exhaust gases emitted by the engine. The changes of EU standard requirements for diesel fuels, implemented in 2000, 2005, and 2009, were directed toward the reduction of the harmfulness of the exhaust gases emitted by the engines. At present, the modification of the conventional properties of diesel fuel that affect the emissions (cetane number, sulfur content, distillation, etc.) is possible to a limited extent only. Therefore, in order to take the maximum advantage of the fuel potential in exhaust emissions reduction, some more unconventional modifications of the fuel should be considered. The application of oxygenated compounds seems to be one of the more promising solutions in this field. The compounds particularly affect a very troublesome component of diesel engine exhaust – i.e., particulate matter. On the basis of physicochemical and environmental parameters, test results described in the literature, as well as price and availability, oxygen compounds belonging to chemical groups such as glycol ethers, maleates, and carbonates were selected for further experimental testing in this study. The study also includes butanol, whose mass production from biomass is being considered. Butanol is closer in terms of its properties to diesel fuel than the currently produced large-scale ethanol. The detailed characteristics of the oxygen com‐ pounds selected for testing are presented in Section 3.2.

The literature presents some test results of maleates as components of diesel fuel. Among them, there are works delivered by Stoner and Lizinger [17], who obtained reduction in PM and NO*x* emissions at the same time by using diethyl maleate and dibutyl maleate. They also tested some glycol ethers, which, however, caused less favorable changes in emissions than maleates. Natarajan et al. [12] analyzed potential oxygenated compounds and, based on their physical and chemical properties, they selected eight of the most suitable oxygenates to be used in diesel fuel. Among them, there was dibutyl maleate. Further, they performed emissions tests in one mode of engine operation with the use of the selected components at the concentration, ensuring 7% of oxygen in the fuel [18]. Dibutyl maleate caused considerable decrease in PM emissions and, at the same time, considerable increase in NO*x* emissions. Based on total PM emissions and other considerations, dibutyl maleate and tripropylene glycol monomethyl ether were identified as the most promising oxygenated compounds for future engine testing. These more extensive engine tests carried out in several engine operating modes confirmed high efficiency of the abovementioned oxygenates in PM emissions reduction and showed that these oxygenates had no unfavorable influence on NO*x* emissions [19].

In the available bibliography, there are some examples of the results obtained in the tests of carbonates as diesel fuel components. Murayama et al. [20] carried out some extensive research on the influence of dimethyl carbonate on the combustion characteristics and emissions from a direct injection (DI) diesel engine. It was found that for the carbonate content in fuel of 10%, the smoke emission was lowered by 35–50%, and also that the extent of the smoke emission reduction was proportional to the oxygenate content. Moreover, it was found that the carbo‐ nate additive caused a significant decrease in the CO and HC concentrations in exhaust gases and a small increase in the NO*x* emissions. Also Akasaka and Sakurai presented in their paper [21] the reduction in smoke emission obtained with the use of an additive from the carbonate group (its name was not mentioned). The research on the influence of oxygenates on the PM emissions in the New European Driving Cycle (NEDC) with the use of the Audi A3 TDI (Euro 2) passenger car were carried out by Delfort et al. [14]. They tested 18 oxygenates, including 5 oxygenates from the chemical family of carbonates. They found that both oxygen content in fuel and the oxygenated compound chemical structure were decisive for the reduction in the PM emissions. Their tests showed that at the same content of different oxygenates in fuel, the highest reduction in the PM emissions was obtained in case of the use of carbonates. Next, from among all tested carbonates, diethyl carbonate and diethoxy-2-ethyl carbonate were the most effective ones, which, when added to the fuel in amount of 5%, caused the reduction in the PM emissions in the NEDC by 17–18%. Substantial reduction in exhaust soot emissions for diesel fuel containing dimethyl carbonate was described by Kocis et al. [22]. They also discussed the potential paths of oxygenated compounds influence on soot production.

toward the reduction of the harmfulness of the exhaust gases emitted by the engines. At present, the modification of the conventional properties of diesel fuel that affect the emissions (cetane number, sulfur content, distillation, etc.) is possible to a limited extent only. Therefore, in order to take the maximum advantage of the fuel potential in exhaust emissions reduction, some more unconventional modifications of the fuel should be considered. The application of oxygenated compounds seems to be one of the more promising solutions in this field. The compounds particularly affect a very troublesome component of diesel engine exhaust – i.e., particulate matter. On the basis of physicochemical and environmental parameters, test results described in the literature, as well as price and availability, oxygen compounds belonging to chemical groups such as glycol ethers, maleates, and carbonates were selected for further experimental testing in this study. The study also includes butanol, whose mass production from biomass is being considered. Butanol is closer in terms of its properties to diesel fuel than the currently produced large-scale ethanol. The detailed characteristics of the oxygen com‐

The literature presents some test results of maleates as components of diesel fuel. Among them, there are works delivered by Stoner and Lizinger [17], who obtained reduction in PM and NO*x* emissions at the same time by using diethyl maleate and dibutyl maleate. They also tested some glycol ethers, which, however, caused less favorable changes in emissions than maleates. Natarajan et al. [12] analyzed potential oxygenated compounds and, based on their physical and chemical properties, they selected eight of the most suitable oxygenates to be used in diesel fuel. Among them, there was dibutyl maleate. Further, they performed emissions tests in one mode of engine operation with the use of the selected components at the concentration, ensuring 7% of oxygen in the fuel [18]. Dibutyl maleate caused considerable decrease in PM emissions and, at the same time, considerable increase in NO*x* emissions. Based on total PM emissions and other considerations, dibutyl maleate and tripropylene glycol monomethyl ether were identified as the most promising oxygenated compounds for future engine testing. These more extensive engine tests carried out in several engine operating modes confirmed high efficiency of the abovementioned oxygenates in PM emissions reduction and showed that

In the available bibliography, there are some examples of the results obtained in the tests of carbonates as diesel fuel components. Murayama et al. [20] carried out some extensive research on the influence of dimethyl carbonate on the combustion characteristics and emissions from a direct injection (DI) diesel engine. It was found that for the carbonate content in fuel of 10%, the smoke emission was lowered by 35–50%, and also that the extent of the smoke emission reduction was proportional to the oxygenate content. Moreover, it was found that the carbo‐ nate additive caused a significant decrease in the CO and HC concentrations in exhaust gases and a small increase in the NO*x* emissions. Also Akasaka and Sakurai presented in their paper [21] the reduction in smoke emission obtained with the use of an additive from the carbonate group (its name was not mentioned). The research on the influence of oxygenates on the PM emissions in the New European Driving Cycle (NEDC) with the use of the Audi A3 TDI (Euro 2) passenger car were carried out by Delfort et al. [14]. They tested 18 oxygenates, including 5 oxygenates from the chemical family of carbonates. They found that both oxygen content in

pounds selected for testing are presented in Section 3.2.

48 Alternative Fuels, Technical and Environmental Conditions

these oxygenates had no unfavorable influence on NO*x* emissions [19].

Glycol ethers are as often as not tested as diesel oxygenated compounds. The aforementioned research, carried out by Delfort et al. [14], showed their moderate efficiency in PM emission reduction. The research conducted by Hallgren and Heywood [23] also showed that glycol ethers decrease PM emissions. Moreover, this research proved that these oxygenates reduce mainly insoluble fraction (soot), whereas soluble organic fraction (SOF) remains intact. Yeh et al. [24] proved that glycol ethers cause not only a reduction in PM emissions but also a reduction in CO and HC emissions and an increase in NO*x* emissions. Favorable effects of glycol ethers on exhaust emissions were also described in papers delivered by Porai et al. [25] and Akasaka and Sakurai [21].

The majority of the published papers concerning the influence of oxygenates on exhaust emissions from diesel engines have reported the results of research conducted under stationary conditions, for one or more engine operating modes. From among the few investigations carried out under transient conditions, aforementioned research performed by Delfort et al. [14] and Yeh et al. [24] should be noted.

The detailed mechanism by which oxygenates reduce PM emissions has not been precisely defined so far. The literature contains contradictory results as to whether the oxygen content in fuel is the only important factor determining PM/smoke emissions, or whether oxygenate molecular structure or other variables also play important roles. Research carried out by Nabi et al. [26] with highly oxygenated diesel fuels containing glycol ethers and carbonates showed that smoke decreased linearly and depended entirely on the oxygen content in the fuel, regardless of the kind of the oxygenate. Another study with highly oxygenated diesel fuels by Mueller and Martin [27] indicates that overall oxygen content is not the only important parameter governing the soot reduction potential of a fuel, and that molecular structure effects may also be significant. Buchholz et al. [28] using selective labeling of carbon atoms in dibutyl maleate molecules proved that the molecular structure and distribution of oxygen within an oxygenated diesel fuel strongly influences the ability of the fuel to reduce PM emissions. In the recent study written by Boot et al. [29], it was shown that the oxygen content has a pronounced effect on PM reduction, but chemical structure effects can be almost of the same order.

The experimental results presented in the chapter were obtained within a research program investigating the effect of different synthetic oxygenates on exhaust emissions from diesel passenger cars. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for further advanced testing and practical application. The research was carried out with oxygenates representing different chemical groups. All the emissions test were conducted over dynamic cycles in a chassis dynamometer (NEDC, FTP-75).

### **3.2. Research methodology**

### *3.2.1. Scope of the research*

The study was performed at the BOSMAL Automotive Research & Development Institute in Bielsko-Biała. They included measurements of toxic exhaust emissions (CO, HC, NO*x*, and PM), CO2 emissions, and fuel consumption on a chassis dynamometer in test cycles for passenger cars with a Euro 4 class diesel engine run on different oxygenated fuel variants. The conducted study was comparative; hence, measurements were also made for cars running on conventional diesel fuel, not containing oxygenated components. The research was staged and includes, in particular:


### *3.2.2. Research fuels*

The study used 12 different synthetic oxygenates representing four chemical groups, such as the glycol ethers, maleates, carbonates, and alcohols. Oxygenated compounds were used in concentrations of 5 and 10%. Selection of components was dictated primarily by their physi‐ cochemical properties (oxygen content, compatibility with diesel fuel, etc.) and the results of tests described in the literature, followed by price and availability. Physicochemical properties of the oxygen compounds used in the study are shown in Table 2. The oxygen content of the compounds used is in the range 21.6–53.3% m/m. Oxygen compounds were labeled in this work with the symbol PT-*X*-*Y*%, where *X* is the number of oxygen compound used in accordance with Table 2, and *Y* is its content by volume.

All research fuels were formulated based on Euro 5 grade diesel fuel. Due to the long duration of the research, and taking into account the aging processes of fuel (change in fuel properties during storage), diesel fuel used was purchased in two tranches, labeled in this work as ON I and ON II. The properties of diesel fuel in both tranches were similar; they have been shown in Tables 3 and 4.

#### The Study on the Influence of Diesel Fuel Oxygenates on Exhaust Emissions http://dx.doi.org/10.5772/62005 51


**content,**

groups. All the emissions test were conducted over dynamic cycles in a chassis dynamometer

The study was performed at the BOSMAL Automotive Research & Development Institute in Bielsko-Biała. They included measurements of toxic exhaust emissions (CO, HC, NO*x*, and PM), CO2 emissions, and fuel consumption on a chassis dynamometer in test cycles for passenger cars with a Euro 4 class diesel engine run on different oxygenated fuel variants. The conducted study was comparative; hence, measurements were also made for cars running on conventional diesel fuel, not containing oxygenated components. The research was staged and

**1.** Preliminary studies (NEDC) aimed to determine the effect of each of the 12 researched oxygenated compounds on the exhaust emissions, thus indicating which of the tested fuel additives are most beneficial for reducing the engine exhaust toxicity. The results of the preliminary research were also used as the basis for determining the unit efficiency of oxygen contained in the fuel to reduce PM emissions as well as for the selection of oxygen

**2.** Investigation of the effect of oxygenates on exhaust emissions, depending on their content

**3.** Investigation of the effect of oxygenates on exhaust emissions, depending on the test cycle

The study used 12 different synthetic oxygenates representing four chemical groups, such as the glycol ethers, maleates, carbonates, and alcohols. Oxygenated compounds were used in concentrations of 5 and 10%. Selection of components was dictated primarily by their physi‐ cochemical properties (oxygen content, compatibility with diesel fuel, etc.) and the results of tests described in the literature, followed by price and availability. Physicochemical properties of the oxygen compounds used in the study are shown in Table 2. The oxygen content of the compounds used is in the range 21.6–53.3% m/m. Oxygen compounds were labeled in this work with the symbol PT-*X*-*Y*%, where *X* is the number of oxygen compound used in

All research fuels were formulated based on Euro 5 grade diesel fuel. Due to the long duration of the research, and taking into account the aging processes of fuel (change in fuel properties during storage), diesel fuel used was purchased in two tranches, labeled in this work as ON I and ON II. The properties of diesel fuel in both tranches were similar; they have been shown

(NEDC, FTP-75).

**3.2. Research methodology**

50 Alternative Fuels, Technical and Environmental Conditions

*3.2.1. Scope of the research*

includes, in particular:

*3.2.2. Research fuels*

in Tables 3 and 4.

compounds for further, more detailed analysis.

accordance with Table 2, and *Y* is its content by volume.

in the fuel (5 or 10% v/v, NEDC).

conditions (NEDC and FTP-75).


**Table 2.** The properties of synthetic oxygenated compounds used in this research


#### The Study on the Influence of Diesel Fuel Oxygenates on Exhaust Emissions http://dx.doi.org/10.5772/62005 53


**Table 3.** Specifications of the first batch of base diesel fuel (ON I)

**% m/m Boiling point, °C**

52 Alternative Fuels, Technical and Environmental Conditions

**Freezing point, °C**

**Flash point, °C**

**Self-ignition temperature, °C**

**Density @ 20°C, kg/m3**

**Viscosity @ 20°C, mm2 /s**

**Cetane number (calculated)**

**Vapor pressure @ 20°C, kPa**

> **Aromatic hydrocarbons**

243 225 281 90 127 117

–78 –10 – 3 –43 –90

121 – >110 – – 34

227 350 – – – 343

963 1064 988 1069 975 810

5.5 – – 0.56 0.78 3.64

58.3 56.8 43.8 10.3 13.8 10.2

<0.001 0.1 (14°C) – 2.4 1.3 0.5

**Cetane number** – 51.8 **Cetane index** – 53.1 **Density @ 20°C** kg/m3 831.2 **Sulfur content** ppm 9.9 **Oxygen content** % m/m 0.0

@ 40°C mm2

**Distillation** E250 % v/v 35.3

E350 % v/v 97.6 T95 C 341.6 FBP C 352.0

Total aromatics % m/m 23.9 Monoaromatics % m/m 21.4

**Unit Value**

/s 4.283

/s 2.773

**Table 2.** The properties of synthetic oxygenated compounds used in this research

**Viscosity** @ 20°C mm2


**Table 4.** Specifications of the second batch of base diesel fuel (ON II)

### *3.2.3. Research conditions*

### *3.2.3.1. Research equipment description*

The research was conducted in the Exhaust Toxicity Laboratory at the BOSMAL Automotive Research & Development Institute in Bielsko-Biała, which has the instrumentation to measure toxic exhaust emissions from vehicles powered by diesel engines and accredited by the TÜV. The course of research in the laboratory is controlled by the measurement management system AVL CESAR. The temperature and humidity at the level required by the testing procedure are maintained by a complete heating, ventilation, and air-conditioning (HVAC) system.

The laboratory is equipped with a SCHENCK 500GS/60 chassis dynamometer (Fig. 4). Chassis dynamometer is a device designed to simulate the resistance of motion (rolling and aerody‐ namic) for a car moving forward on a flat road and the inertia of the vehicle.

The core elements of the dynamometer include:


Dynamometer is equipped with a parameter adjustment system for the driver (Driver Guiding Unit LMC 68/40). The operation of this device consists in presenting (in advance) the required driving performance parameters as a function of time to the driver: speed, moving and stopping points for the vehicle, as well as the time to push the clutch down and shifting gears. In addition, the current time of the test as well as the number and total time of breaching the preset parameters of the drive cycle are given.

**Figure 4.** Chassis dynamometer SCHENCK 500GS/60 in BOSMAL Automotive Research & Development Institute

The measurement of toxic exhaust emissions during the driving tests was carried out with an exhaust collection and sampling system with a Venturi nozzle – "Quadro Venturi" (CFV-CVS) of the AVL CEC-Q20 type, equipped with a full-flow exhaust dilution tunnel AVL CET-LD/20. A sample of the mixture of exhaust and air, in proportion to the flow rate of the mixture, is continuously taken and collected in a sampling bag during the driving test.

After completing the test, the contents of the measurement bags, which is a mixture of exhaust gases and ambient air, is directed to a set of analyzers, which determine the concentration of each of the gaseous exhaust components. In accordance with the procedure of measuring emissions from vehicles equipped with CI engines, the exception is the measurement of the concentration of HC, which is done by drawing a sample through a heated line directly from the dilution tunnel. The sample for measuring exhaust emissions of PM is also taken from the dilution tunnel using a particulate sampling system AVL CEP-LD/100. The concentration measurements of gaseous exhaust components was performed through a set of AVL CEB 600 exhaust gas analyzers, which includes the Rosemount NGA 2000 device.

### *3.2.3.2. Drive cycle: NEDC*

The laboratory is equipped with a SCHENCK 500GS/60 chassis dynamometer (Fig. 4). Chassis dynamometer is a device designed to simulate the resistance of motion (rolling and aerody‐

**•** A set of rollers with individual ball bearings, combined with a system of clutches and a belt

**•** A set of controls and measurement devices; the entire operation of the dynamometer (e.g. setting the inertial mass, characterization, calibration, etc.) is done via its own test bench

Dynamometer is equipped with a parameter adjustment system for the driver (Driver Guiding Unit LMC 68/40). The operation of this device consists in presenting (in advance) the required driving performance parameters as a function of time to the driver: speed, moving and stopping points for the vehicle, as well as the time to push the clutch down and shifting gears. In addition, the current time of the test as well as the number and total time of breaching the

**Figure 4.** Chassis dynamometer SCHENCK 500GS/60 in BOSMAL Automotive Research & Development Institute

The measurement of toxic exhaust emissions during the driving tests was carried out with an exhaust collection and sampling system with a Venturi nozzle – "Quadro Venturi" (CFV-CVS)

**•** A set of rotating weights, used for mapping the inertial mass of the tested vehicle,

namic) for a car moving forward on a flat road and the inertia of the vehicle.

The core elements of the dynamometer include:

54 Alternative Fuels, Technical and Environmental Conditions

**•** DC motor fitted with a thyristor control system,

preset parameters of the drive cycle are given.

drive, powered by a DC motor,

control computer.

Most measurements of exhaust emissions are based on NEDC, introduced in the European Union on January 1, 2000, as a vehicle certification test. This cycle (Fig. 5) consists of two parts or phases (subtests): the UDC (Urban Driving Cycle) and the EUDC (Extra Urban Driving Cycle). **3.2.3.2. Drive cycle: NEDC**  Most measurements of exhaust emissions are based on NEDC, introduced in the European Union on January

During the tests, the ambient temperature was 22–23°C, where the allowed temperature range for the test procedure is between 20 and 30°C. Before each test, the vehicle was conditioned in a laboratory environment. One test was performed per day. After each change of the fuel, the car also passed a whole cycle without the measurement of emissions to remove any residue of the previous fuel from the supply system, and the proper test was carried out the next day after reconditioning. 1, 2000, as a vehicle certification test. This cycle (Fig. 5) consists of two parts or phases (subtests): the UDC (Urban Driving Cycle) and the EUDC (Extra Urban Driving Cycle). During the tests, the ambient temperature was 22–23°C, where the allowed temperature range for the test procedure is between 20 and 30°C. Before each test, the vehicle was conditioned in a laboratory environment. One test was performed per day. After each change of the fuel, the car also passed a whole cycle without the measurement of emissions to remove any residue of the previous fuel from the supply system, and the proper test was carried out the next day after reconditioning.

The NEDC intake of the analyzed exhaust gas starts immediately after starting the engine of the vehicle. The first phase (UDC) is composed of four elementary tests repeated in succession. Due to prior conditioning, the engine and the vehicle at the beginning of the UDC phase are at the ambient temperature, thus the start of the engine is cold, just as in real life at start-up after a long (e.g. overnight) parking. During the engine cycle, the temperature of the engine oil, engine coolant, and exhaust gases increases. The EUDC phase starts immediately after the end of the UDC phase, and therefore during the EUDC, the vehicle engine has warmed to operating temperature. In this phase, there are longer periods of operation of the engine at a constant speed and the vehicle

The American federal test FTP-75 (Federal Test Procedure) is used in the US for the measurement of exhaust emissions by light-duty type vehicles and has been in force since 1996. This test consists of three phases (Fig. 6):

12

**Figure 5.** NEDC drive cycle according to the 98/69/EC directive **Figure 5.** NEDC drive cycle according to the 98/69/EC directive

speed reaches a value much higher than that in the UDC.

**3.2.3.3. Drive cycle: FTP-75** 

 cold start phase, transient phase, hot start phase.

The intake of the analyzed exhaust gas starts immediately after starting the engine of the vehicle. The first phase (UDC) is composed of four elementary tests repeated in succession. Due to prior conditioning, the engine and the vehicle at the beginning of the UDC phase are at the ambient temperature, thus the start of the engine is cold, just as in real life at start-up after a long (e.g. overnight) parking. During the engine cycle, the temperature of the engine oil, engine coolant, and exhaust gases increases. The EUDC phase starts immediately after the end of the UDC phase, and therefore during the EUDC, the vehicle engine has warmed to operating temperature. In this phase, there are longer periods of operation of the engine at a constant speed and the vehicle speed reaches a value much higher than that in the UDC.

### *3.2.3.3. Drive cycle: FTP-75*

The American federal test FTP-75 (Federal Test Procedure) is used in the US for the measure‐ ment of exhaust emissions by light-duty type vehicles and has been in force since 1996. This test consists of three phases (Fig. 6):


**Figure 6.** The result of an American FTP-75 drive cycle

A ten-minute break is made between the phases 2 and 3, during which the engine is switched off. The characteristics of the FTP-75 test are:


### *3.2.3.4. Test vehicle*

The intake of the analyzed exhaust gas starts immediately after starting the engine of the vehicle. The first phase (UDC) is composed of four elementary tests repeated in succession. Due to prior conditioning, the engine and the vehicle at the beginning of the UDC phase are at the ambient temperature, thus the start of the engine is cold, just as in real life at start-up after a long (e.g. overnight) parking. During the engine cycle, the temperature of the engine oil, engine coolant, and exhaust gases increases. The EUDC phase starts immediately after the end of the UDC phase, and therefore during the EUDC, the vehicle engine has warmed to operating temperature. In this phase, there are longer periods of operation of the engine at a constant speed and the vehicle speed reaches a value much higher than that in the UDC.

The American federal test FTP-75 (Federal Test Procedure) is used in the US for the measure‐ ment of exhaust emissions by light-duty type vehicles and has been in force since 1996. This

A ten-minute break is made between the phases 2 and 3, during which the engine is switched

*3.2.3.3. Drive cycle: FTP-75*

**•** cold start phase,

**•** transient phase,

**•** hot start phase.

test consists of three phases (Fig. 6):

56 Alternative Fuels, Technical and Environmental Conditions

**Figure 6.** The result of an American FTP-75 drive cycle

off. The characteristics of the FTP-75 test are:

**•** distance traversed: 17.77 km,

**•** time duration: 1874 s,

**•** average speed: 43.1 km/h.

The study used a Fiat Panda 1.3 16v Multijet vehicle, which at the start of the research represented the level of technological advancement of vehicle technologies. The car was equipped with a turbocharged diesel engine fueled in a common rail system. The car had controlled EGR system and catalytic exhaust aftertreatment, and its exhaust emissions met the Euro 4 standard. Key parameters of the test vehicle are presented in Table 5.

Due to the necessity of frequent changes in the fuel type for the test vehicle, and to avoid contamination of the test fuel with the previous fuel remaining in the fuel system, the fuel supply system of the vehicle was modified. A portable external fuel tank with its own electric low-pressure pump was used, delivering fuel directly into the high-pressure pump nozzle. Thanks to this, the length of the low-pressure fuel lines (i.e. the distance between low-pressure pump and the high-pressure pump) has been reduced several times. Several elements with a large capacity (the factory-issued fuel tank, low-pressure pump and fuel lines leading to the high-pressure pump), which could retain the fuel of the preceding tests, have been eliminated from the fuel supply system.


**Table 5.** Specifications of the test vehicle

### **3.3. Preliminary studies of the effect of oxygenated compounds on exhaust emissions**

The aim of the research was to conduct a preliminary selection of oxygenates as fuel additives to ensure the most favorable changes in the composition of exhaust gases. These studies used 12 selected oxygenated compounds belonging to the following chemical groups: glycol ethers, maleates, carbonates, and alcohols. The preliminary studies testing the effectiveness of selected fuel oxygenates have been made under NEDC conditions, with a separate measurement of emission components in both its phases (UDC and EUDC). The emissions of CO, HC, NO*x*, PM, and CO2 were measured. The oxygenated fuels used for the study were blended using two base diesel fuels: ON I and ON II. PT-1 to PT-6 fuels contained the ON I diesel fuel and the others, i.e. PT-7 to PT-12 the ON II diesel fuel. Vehicle emission test results of the researched individual oxygenated fuels should therefore be referred to the results obtained for the corresponding base diesel fuels.

Table 6. Specifications of the test vehicle

tests, have been eliminated from the fuel supply system.

Vehicle type Passenger car Dry weight 950 kg

Displacement 1.3 dm<sup>3</sup>

Calibrated to EURO 4

Engine type Diesel, 4-cylinder in-line

Max. power 51 kW @ 4000 rpm Max. torque 145 Nm @ 1500 rpm

Emission control Oxidation catalyst

#### *3.3.1. Carbon monoxide emissions* emission components in both its phases (UDC and EUDC). The emissions of CO, HC, NOx, PM, and CO2 were measured.

emissions.

ethers.

CO [g/km]

0,00 0,05 0,10 0,15 0,20 0,25 0,30 0,35

> ON I PT-1- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

3.3.2. Hydrocarbons emissions

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 9. The average emissions of CO in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Same as for CO, the UDC phase saw a significantly lower HC emission for most of the oxygenated fuels (Fig. 10). Again, the relationship of fuel cetane number and the levels of emission reduction has been noted. When using fuels containing maleates, carbonates, and *n*-butanol, a slightly higher emission of HC has been observed than for neat diesel fuel.

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

CO emission in the UDC phase (Fig. 7) was reduced when using most of the fuels containing glycol ethers, in particular for fuels containing oxygenated components 3–5. Note that these components had a very high cetane number and physical properties similar to those of diesel fuel. It appears that in the UDC phase conditions, so during engine warm-up, increased ability to self-ignition of fuel is essential to CO emission reduction. This is indicated by the result obtained for a fuel containing component 5 with a distinctly lower oxygen content than the components 3 and 4, as well as the results of studies on the effect of cetane number on emis‐ sions of CO made using fuels containing no oxygen [30, 31]. For fuels containing maleates and carbonates, the obtained CO emission levels were higher than for pure diesel. Maleates were characterized by a moderate amount of oxygen with a similar cetane number to that of diesel fuel,andfor carbonates,lowcetanenumberwas compensatedbyalargeoxygencontent.Higher CO emissions have also been observed for the fuel containing *n*-butanol, which is a compo‐ nent with a low cetane number, relatively low oxygen content, and much lower boiling temperature than diesel fuel. contained the ON I diesel fuel and the others, i.e. PT-7 to PT-12 the ON II diesel fuel. Vehicle emission test results of the researched individual oxygenated fuels should therefore be referred to the results obtained for the corresponding base diesel fuels. 3.3.1. Carbon monoxide emissions CO emission in the UDC phase (Fig. 7) was reduced when using most of the fuels containing glycol ethers, in particular for fuels containing oxygenated components 3–5. Note that these components had a very high cetane number and physical properties similar to those of diesel fuel. It appears that in the UDC phase conditions, so during engine warmup, increased ability to self-ignition of fuel is essential to CO emission reduction. This is indicated by the result obtained for a fuel containing component 5 with a distinctly lower oxygen content than the components 3 and 4, as well as the results of studies on the effect of cetane number on emissions of CO made using fuels containing oxygen [30, 31]. For fuels containing maleates and carbonates, the obtained CO emission levels were higher than for pure diesel. Maleates were characterized by a moderate amount of oxygen with a similar cetane number to that of diesel fuel, and for carbonates, low cetane number was compensated by a large oxygen content. Higher CO emissions have also been observed for the fuel containing *n*-butanol, which is a component with a low cetane number, relatively low oxygen content, and much lower boiling temperature than diesel fuel.

tank, low-pressure pump and fuel lines leading to the high-pressure pump), which could retain the fuel of the preceding

Injection/combustion type Direct injection common rail, turbocharged (intercooled)

Exhaust gas recirculation Electronically controlled (closed-loop)

3.3. Preliminary studies of the effect of oxygenated compounds on exhaust emissions

to the following chemical groups: glycol ethers, maleates, carbonates, and alcohols. The preliminary studies testing the effectiveness of selected fuel oxygenates have been made under NEDC conditions, with a separate measurement of

The oxygenated fuels used for the study were blended using two base diesel fuels: ON I and ON II. PT-1 to PT-6 fuels

**Figure 7.** CO emissions during the UDC for conventional diesel fuels (ON I and ON II) and oxygenated fuels contain‐ ing individual oxygenates at a concentration of 5% v/v; PT-1-5% to PT-6-5% were formulated on the basis of diesel fuel ON I and PT-7-5% to PT-12-5% were based on the ON II fuel were based on the ON II fuel In the EUDC phase, the CO emissions are reduced to very low values (Fig. 8), mainly due to a stabilized thermal state of the engine and the effective operation of the catalytic converter. All fuels, except PT-12-5%, showed a similar level of

oxygenates at a concentration of 5% v/v; PT-1-5% to PT-6-5% were formulated on the basis of diesel fuel ON I and PT-7-5% to PT-12-5%

Very large disparities in CO emissions between phases UDC and EUDC (a difference of more than two orders of magnitude) mean that the average CO emissions in the NEDC (Fig. 9) are determined by the UDC phase. Therefore, the best performance across the NEDC test was reported for the same fuel as for the UDC phase, thus containing glycol

Figure 8. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 8.** CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

Figure 7. CO emissions during the UDC for conventional diesel fuels (ON I and ON II) and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v; PT-1-5% to PT-6-5% were formulated on the basis of diesel fuel ON I and PT-7-5% to PT-12-5%

In the EUDC phase, the CO emissions are reduced to very low values (Fig. 8), mainly due to a stabilized thermal state of the engine and the effective operation of the catalytic converter. All fuels, except PT-12-5%, showed a similar level of

In the EUDC phase, the CO emissions are reduced to very low values (Fig. 8), mainly due to a stabilized thermal state of the engine and the effective operation of the catalytic converter. All fuels, except PT-12-5%, showed a similar level of emissions. 0,000 ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II

Very large disparities in CO emissions between phases UDC and EUDC (a difference of more than two orders of magnitude) mean that the average CO emissions in the NEDC (Fig. 9) are determined by the UDC phase. Therefore, the best performance over the NEDC was reported for the same fuel as for the UDC phase, thus containing glycol ethers. Figure 8. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v Very large disparities in CO emissions between phases UDC and EUDC (a difference of more than two orders of magnitude) mean that the average CO emissions in the NEDC (Fig. 9) are determined by the UDC phase. Therefore, the best performance across the NEDC test was reported for the same fuel as for the UDC phase, thus containing glycol

Figure 9. The average emissions of CO in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 9.** The average emissions of CO in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

### *3.3.2. Hydrocarbons emissions*

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

0,00 0,01 0,02 0,03 0,04 0,05

HC [g/km]

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

concentration of 5% v/v

HC [g/km]

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 11. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11).

The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

3.3.2. Hydrocarbons emissions

were based on the ON II fuel

emissions.

0,001 0,002 0,003 0,004 0,005 0,006

CO [g/km]

ethers.

*3.3.1. Carbon monoxide emissions*

diesel fuels.

Table 6. Specifications of the test vehicle

58 Alternative Fuels, Technical and Environmental Conditions

3.3.1. Carbon monoxide emissions

content, and much lower boiling temperature than diesel fuel.

temperature than diesel fuel.

CO [g/km]

0,0 0,2 0,4 0,6 0,8 1,0

emissions.

CO [g/km]

0,000 0,001 0,002 0,003 0,004 0,005 0,006

oxygenates at a concentration of 5% v/v

ethers.

CO [g/km]

0,00 0,05 0,10 0,15 0,20 0,25 0,30 0,35

> ON I PT-1- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

3.3.2. Hydrocarbons emissions

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 9. The average emissions of CO in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Same as for CO, the UDC phase saw a significantly lower HC emission for most of the oxygenated fuels (Fig. 10). Again, the relationship of fuel cetane number and the levels of emission reduction has been noted. When using fuels containing maleates, carbonates, and *n*-butanol, a slightly higher emission of HC has been observed than for neat diesel fuel.

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

concentration of 5% v/v

ON I PT-1- 5%

were based on the ON II fuel

ON I and PT-7-5% to PT-12-5% were based on the ON II fuel

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 8.** CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual

PT-7- 5%

PT-8- 5%

Figure 8. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

Very large disparities in CO emissions between phases UDC and EUDC (a difference of more than two orders of magnitude) mean that the average CO emissions in the NEDC (Fig. 9) are determined by the UDC phase. Therefore, the best performance across the NEDC test was reported for the same fuel as for the UDC phase, thus containing glycol

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 7.** CO emissions during the UDC for conventional diesel fuels (ON I and ON II) and oxygenated fuels contain‐ ing individual oxygenates at a concentration of 5% v/v; PT-1-5% to PT-6-5% were formulated on the basis of diesel fuel

PT-7- 5%

PT-8- 5%

In the EUDC phase, the CO emissions are reduced to very low values (Fig. 8), mainly due to a stabilized thermal state of the engine and the effective operation of the catalytic converter. All fuels, except PT-12-5%, showed a similar level of

Figure 7. CO emissions during the UDC for conventional diesel fuels (ON I and ON II) and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v; PT-1-5% to PT-6-5% were formulated on the basis of diesel fuel ON I and PT-7-5% to PT-12-5%

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

CO emission in the UDC phase (Fig. 7) was reduced when using most of the fuels containing glycol ethers, in particular for fuels containing oxygenated components 3–5. Note that these components had a very high cetane number and physical properties similar to those of diesel fuel. It appears that in the UDC phase conditions, so during engine warm-up, increased ability to self-ignition of fuel is essential to CO emission reduction. This is indicated by the result obtained for a fuel containing component 5 with a distinctly lower oxygen content than the components 3 and 4, as well as the results of studies on the effect of cetane number on emis‐ sions of CO made using fuels containing no oxygen [30, 31]. For fuels containing maleates and carbonates, the obtained CO emission levels were higher than for pure diesel. Maleates were characterized by a moderate amount of oxygen with a similar cetane number to that of diesel fuel,andfor carbonates,lowcetanenumberwas compensatedbyalargeoxygencontent.Higher CO emissions have also been observed for the fuel containing *n*-butanol, which is a compo‐ nent with a low cetane number, relatively low oxygen content, and much lower boiling

tests, have been eliminated from the fuel supply system.

Vehicle type Passenger car Dry weight 950 kg

Displacement 1.3 dm<sup>3</sup>

Calibrated to EURO 4

Engine type Diesel, 4-cylinder in-line

Max. power 51 kW @ 4000 rpm Max. torque 145 Nm @ 1500 rpm

Emission control Oxidation catalyst

tank, low-pressure pump and fuel lines leading to the high-pressure pump), which could retain the fuel of the preceding

Injection/combustion type Direct injection common rail, turbocharged (intercooled)

Exhaust gas recirculation Electronically controlled (closed-loop)

3.3. Preliminary studies of the effect of oxygenated compounds on exhaust emissions

The aim of the research was to conduct a preliminary selection of oxygenates as fuel additives to ensure the most favorable changes in the composition of exhaust gases. These studies used 12 selected oxygenated compounds belonging to the following chemical groups: glycol ethers, maleates, carbonates, and alcohols. The preliminary studies testing the effectiveness of selected fuel oxygenates have been made under NEDC conditions, with a separate measurement of emission components in both its phases (UDC and EUDC). The emissions of CO, HC, NOx, PM, and CO2 were measured. The oxygenated fuels used for the study were blended using two base diesel fuels: ON I and ON II. PT-1 to PT-6 fuels contained the ON I diesel fuel and the others, i.e. PT-7 to PT-12 the ON II diesel fuel. Vehicle emission test results of the researched individual oxygenated fuels should therefore be referred to the results obtained for the corresponding base

CO emission in the UDC phase (Fig. 7) was reduced when using most of the fuels containing glycol ethers, in particular for fuels containing oxygenated components 3–5. Note that these components had a very high cetane number and physical properties similar to those of diesel fuel. It appears that in the UDC phase conditions, so during engine warmup, increased ability to self-ignition of fuel is essential to CO emission reduction. This is indicated by the result obtained for a fuel containing component 5 with a distinctly lower oxygen content than the components 3 and 4, as well as the results of studies on the effect of cetane number on emissions of CO made using fuels containing oxygen [30, 31]. For fuels containing maleates and carbonates, the obtained CO emission levels were higher than for pure diesel. Maleates were characterized by a moderate amount of oxygen with a similar cetane number to that of diesel fuel, and for carbonates, low cetane number was compensated by a large oxygen content. Higher CO emissions have also been observed for the fuel containing *n*-butanol, which is a component with a low cetane number, relatively low oxygen

> the relationship of fuel cetane number and the levels of emission reduction has been noted. When using fuels containing maleates, carbonates, and *n*-butanol, a slightly higher emission of HC has been observed than for neat diesel fuel. Same as for CO, the UDC phase saw a significantly lower HC emission for most of the oxygenated fuels (Fig. 10). Again, the relationship of fuel cetane number and the levels of emission reduction has been noted. When using fuels containing maleates, carbonates, and *n*butanol, a slightly higher emission of HC has been observed than for neat diesel fuel.

Same as for CO, the UDC phase saw a significantly lower HC emission for most of the oxygenated fuels (Fig. 10). Again,

concentration of 5% v/v **Figure 10.** HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

at the level similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%).

Figure 10. HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

at the level similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%).

PT-5- 5%

0,00

0,06

0,02 0,03

0,000

0,006 0,008

0,04 0,06 0,08 0,10 0,12

0,12

HC [g/km]

HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained at the level similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%). Figure 10. HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in 0,00 0,02 0,04 ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II HC [g/km]

PT-6- 5%

PT-7- 5%

PT-8- 5%

the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained

greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause

HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11).

Figure 10. HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

Figure 11. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 11.** CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v 0,002 0,004

The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11). 0,04 0,05 The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11). ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II Figure 11. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point)

**Figure 12.** The average emissions of HC in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

Figure 12. The average emissions of HC in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

0,20 0,25 NOx [g/km]Figure 13. NOx emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 13.** NO*x* emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

#### *3.3.3. Nitrogen oxides emissions* 0,05 0,10 0,15 0,30

0,25

concentration of 5% v/v

0,05

0,30

individual oxygenates at a concentration of 5% v/v

3.3.3. Nitrogen oxides emissions

HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained at the level

PT-6- 5%

PT-6- 5%

PT-7- 5%

PT-7- 5%

PT-8- 5%

Figure 10. HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-8- 5%

Figure 10. HC emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained

HC emissions in the EUDC phase are roughly an order of magnitude lower than in the UDC phase (Fig. 11), which is the result of steady thermal state of the engine, the effective operation of the catalytic converter and less dynamic changes in the operating conditions of the engine. For all oxygenated fuels, the HC emissions were reduced, or at least maintained

PT-9- 5%

PT-9- 5%

PT-10-5%

PT-10-5%

PT-11-5%

PT-11-5%

PT-12-5%

PT-12-5% ON II

ON II

similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%).

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

PT-4- 5%

at the level similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%).

at the level similar to that of diesel fuel (PT-1-5%, PT-9-5%, PT-11-5%).

PT-4- 5%

PT-5- 5%

PT-5- 5%

0,00 0,02 0,04 0,06 0,08 0,10 0,12

0,080,10

0,12

0,00 0,02 0,04 0,06

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

oxygenates at a concentration of 5% v/v

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

0,00 0,01 0,02 0,03 0,04 0,05

0,00 0,01 0,02 0,03 0,04 0,05

containing components 9 and 11).

HC [g/km]

HC [g/km]

ON I PT-1- 5%

ON I PT-1- 5%

PT-2- 5%

PT-2- 5%

fuels containing individual oxygenates at a concentration of 5% v/v

PT-3- 5%

PT-3- 5%

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

PT-6- 5%

PT-6- 5%

**Figure 12.** The average emissions of HC in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated

PT-7- 5%

PT-7- 5%

PT-8- 5%

PT-8- 5%

PT-9- 5%

PT-9- 5%

PT-10-5%

PT-10-5%

PT-11-5%

PT-11-5%

PT-12-5%

PT-12-5% ON II

ON II

concentration of 5% v/v

concentration of 5% v/v

HC [g/km]

HC [g/km]

ON I PT-1- 5%

ON I PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 11.** CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual

The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause HC level to remain similar to or slightly higher than that of diesel fuel (fuels

PT-6- 5%

PT-5- 5%

PT-7- 5%

PT-8- 5%

Figure 11. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11).

HC level to remain similar to or slightly higher than that of diesel fuel (fuels containing components 9 and 11).

PT-7- 5%

The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause

PT-8- 5%

Figure 11. CO emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

The average HC emission in the NEDC test (Fig. 12) is determined mainly by the UDC phase. Generally, it can be said that all tested glycol ethers, with the exception of the compound number 1, produced a significant (approximately 30%) reduction in HC emissions. The said ether has a lower cetane number and physical properties (viscosity, boiling point) greatly deviating from the characteristics of diesel fuel. In contrast, other fuels containing oxygenated compounds cause

PT-9- 5%

PT-9- 5%

PT-10-5%

PT-10-5%

PT-11-5%

PT-11-5%

PT-12-5%

PT-12-5% ON II

ON II

concentration of 5% v/v

concentration of 5% v/v

HC [g/km]

HC [g/km]

ON I PT-1- 5%

60 Alternative Fuels, Technical and Environmental Conditions

ON I PT-1- 5%

> In the UDC phase, a very slight difference, not exceeding a few percent, was found in NO*<sup>x</sup>* emissions for various fuels (Fig. 13). In the EUDC phase, for all the tested oxygenated fuels slightly higher NO*x* emissions than for diesel fuel were observed (Fig. 14), but these differences can be considered minor. 0,00 ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II Figure 13. NOx emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a 0,10 0,15 0,20 NOx [g/km]

Figure 14. NOx emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 14.** NO*x* emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v created according to the *prompt* mechanism as well as by locally leaner air–fuel mixture, allowing for burning more fuel and achieving higher local temperatures in the combustion chamber. One can assume that the smaller intensity of the formation of NOx was the effect of a high cetane number of fuels containing the components 1–6. This was confirmed in

The average NOx emission in the NEDC for most oxygenated fuels was slightly (only a few percent) higher than the recorded emissions when powered by diesel fuel alone (Fig. 15); for other oxygenated fuels, the emission values remained in line with diesel fuel. These results confirm the limited impact of fuel on the engine NOx emission level (downstream the outlet valve). It should be added that the highest NOx emissions were observed for fuel with the highest oxygen content, which may be explained by a better availability of oxygen in the zone where nitrogen oxides are created according to the *prompt* mechanism as well as by locally leaner air–fuel mixture, allowing for burning more fuel and achieving higher local temperatures in the combustion chamber. One can assume that the smaller intensity of the formation of NOx was the effect of a high cetane number of fuels containing the components 1–6. This was confirmed in studies using fuels containing no oxygen [31]. The average NO*x* emission in the NEDC for most oxygenated fuels was slightly (only a few percent) higher than the recorded emissions when powered by diesel fuel alone (Fig. 15); for other oxygenated fuels, the emission values remained in line with diesel fuel. These results confirm the limited impact of fuel on the engine NO*x* emission level (downstream the outlet valve). It should be added that the highest NO*x* emissions were observed for fuel with the highest oxygen content, which may be explained by a better availability of oxygen in the zone where nitrogen oxides are created according to the *prompt* mechanism as well as by locally leaner air–fuel mixture, allowing for burning more fuel and achieving higher local tempera‐ tures in the combustion chamber. One can assume that the smaller intensity of the formation of NO*x* was the effect of a high cetane number of fuels containing the components 1–6. This was confirmed in studies using fuels containing no oxygen [31]. studies using fuels containing no oxygen [31].

0,15

0,25 0,30 0,35

*n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those Figure 15. The average NOx emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 15.** The average NO*<sup>x</sup>* emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

### *3.3.4. Particulate matter emissions* of the diesel fuel, were not an obstacle in PM emission reduction. 3.3.4. Particulate matter emissions

0,008

PM emissions in the UDC phase was lower for all oxygenated fuels (Fig. 16), except PT-12-5% containing *n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those of the diesel fuel, were not an obstacle in PM emission reduction. During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17) than in UDC. Classification of oxygenates in terms of efficacy was similar to the one in the UDC phase, where the most effective component (11) lowered PM emissions by 40%. PM emission level when running on diesel fuel was higher in the EUDC phase than in the UDC phase, whereas for oxygenated fuels, it was roughly similar in both phases, and therefore the application of oxygenated fuels resulted in a greater reduction in PM emissions in the EUDC phase. On average, over the whole NEDC, oxygenated fuels achieved at least a few percent of reduction in PM emissions (Fig. 18). PM emissions in the UDC phase was lower for all oxygenated fuels (Fig. 16), except PT-12-5% containing *n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those of the diesel fuel, were not an obstacle in PM emission reduction.

During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17)

Figure 16. PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v **Figure 16.** PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v 0,004 0,006

During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17) than in UDC. Classification of oxygenates in terms of efficacy was similar to the one in the UDC phase, where the most effective component (11) lowered PM emissions by 40%. 0,000 0,002 ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II

PM emission level when running on diesel fuel was higher in the EUDC phase than in the UDC phase, whereas for oxygenated fuels, it was roughly similar in both phases, and therefore the Figure 16. PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

0,004 0,006 0,008 PM [g/km]Figure 17. PM emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a **Figure 17.** PM emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

application of oxygenated fuels resulted in a greater reduction in PM emissions in the EUDC phase. On average, over the whole NEDC, oxygenated fuels achieved at least a few percent of reduction in PM emissions (Fig. 18). 0,000 0,002 ON I PT-1- 5% PT-2- 5% PT-3- 5% PT-4- 5% PT-5- 5% PT-6- 5% PT-7- 5% PT-8- 5% PT-9- 5% PT-10-5% PT-11-5% PT-12-5% ON II 0,014 0,016 0,018

Figure 17. PM emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

individual oxygenates at a concentration of 5% v/v **Figure 18.** The average PM emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v CO2 emissions (Fig. 19) and fuel consumption (Fig. 20) in the NEDC was only slightly higher – in the range of

Figure 18. The average PM emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Glycol ethers, which for the previously analyzed exhaust gas components cause the most favorable changes, were less

effective for PM emissions. The greatest reduction in PM emissions was obtained for carbonates and for maleates. The use of *n*-butanol resulted in the lowest reduction in PM emissions of the tested fuels with oxygenated compounds. 3.3.5. CO2 emissions and fuel consumption Glycol ethers, which for the previously analyzed exhaust gas components cause the most favorable changes, were less effective for PM emissions. The greatest reduction in PM emis‐ sions was obtained for carbonates and for maleates. The use of *n*-butanol resulted in the lowest reduction in PM emissions of the tested fuels with oxygenated compounds. 100 120 140

#### CO2 emissions (Fig. 19) and fuel consumption (Fig. 20) in the NEDC was only slightly higher – in the range of measurement uncertainty – for oxygenated fuel. *3.3.5. CO2 emissions and fuel consumption* 60 80 CO2 [g/km]

0

CO2 [g/km]

ON I PT-1- 5%

ON I PT-1- 5%

> PT-2- 5%

PT-2- 5%

3.3.5. CO2 emissions and fuel consumption

measurement uncertainty – for oxygenated fuel.

PT-3- 5%

PT-3- 5%

> PT-4- 5%

PT-4- 5%

> PT-5- 5%

PT-5- 5%

> PT-6- 5%

PT-7- 5%

PT-7- 5%

> PT-8- 5%

PT-8- 5%

> PT-9- 5%

PT-9- 5%

> PT-10-5%

PT-10-5%

> PT-11-5%

> PT-11-5%

> > PT-12-5%

> > PT-12-5%

> > > ON II

ON II

concentration of 5% v/v

0,008 0,010 0,012

PM [g/km]

concentration of 5% v/v

*3.3.4. Particulate matter emissions*

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016

concentration of 5% v/v

concentration of 5% v/v

oxygenates at a concentration of 5% v/v

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016

PM [g/km]

emissions by 40%.

PM [g/km]

ON I PT-1- 5%

ON I PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 16.** PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual

During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17) than in UDC. Classification of oxygenates in terms of efficacy was similar to the one in the UDC phase, where the most effective component (11) lowered PM

PT-6- 5%

PT-5- 5%

PM emission level when running on diesel fuel was higher in the EUDC phase than in the UDC phase, whereas for oxygenated fuels, it was roughly similar in both phases, and therefore the

PT-7- 5%

PT-7- 5%

PT-8- 5%

Figure 16. PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-8- 5%

Figure 16. PM emissions during the UDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-9- 5%

PT-9- 5%

PT-10-5%

PT-10-5%

PT-11-5%

PT-11-5%

PT-12-5%

PT-12-5% ON II

ON II

0,00 0,05 0,10 0,15 0,20 0,25 0,30 0,35

0,00 0,05 0,10 0,15 0,20 0,25 0,30 0,35

NOx [g/km]

NOx [g/km]

ON I PT-1- 5%

62 Alternative Fuels, Technical and Environmental Conditions

PT-2- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

individual oxygenates at a concentration of 5% v/v

3.3.4. Particulate matter emissions

containing individual oxygenates at a concentration of 5% v/v

3.3.4. Particulate matter emissions

ON I PT-1- 5%

PT-3- 5%

of the diesel fuel, were not an obstacle in PM emission reduction.

of the diesel fuel, were not an obstacle in PM emission reduction.

PT-3- 5%

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

PT-6- 5%

PT-6- 5%

PT-7- 5%

PT-7- 5%

PT-8- 5%

Figure 15. The average NOx emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

PM emissions in the UDC phase was lower for all oxygenated fuels (Fig. 16), except PT-12-5% containing *n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those

PT-8- 5%

Figure 15. The average NOx emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17) than in UDC. Classification of oxygenates in terms of efficacy was similar to the one in the UDC phase, where the most

PM emissions in the UDC phase was lower for all oxygenated fuels (Fig. 16), except PT-12-5% containing *n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those

PM emission level when running on diesel fuel was higher in the EUDC phase than in the UDC phase, whereas for oxygenated fuels, it was roughly similar in both phases, and therefore the application of oxygenated fuels resulted in a greater reduction in PM emissions in the EUDC phase. On average, over the whole NEDC, oxygenated fuels achieved at

During the EUDC phase, the impact of oxygenated fuels on emissions of PM was even more favorable and clear (Fig. 17) than in UDC. Classification of oxygenates in terms of efficacy was similar to the one in the UDC phase, where the most

PM emission level when running on diesel fuel was higher in the EUDC phase than in the UDC phase, whereas for oxygenated fuels, it was roughly similar in both phases, and therefore the application of oxygenated fuels resulted in a greater reduction in PM emissions in the EUDC phase. On average, over the whole NEDC, oxygenated fuels achieved at

PT-9- 5%

PT-9- 5%

PT-10-5%

PT-10-5%

PT-11-5%

PT-11-5%

PT-12-5%

PT-12-5% ON II

ON II

diesel fuel, were not an obstacle in PM emission reduction.

least a few percent of reduction in PM emissions (Fig. 18).

effective component (11) lowered PM emissions by 40%.

least a few percent of reduction in PM emissions (Fig. 18).

effective component (11) lowered PM emissions by 40%.

PM emissions in the UDC phase was lower for all oxygenated fuels (Fig. 16), except PT-12-5% containing *n*-butanol. It may be noted that the largest reduction in PM emissions was observed for fuels with the highest oxygen content. Among fuels with a similar oxygen content, the most effective in emission reduction were components with lower cetane number. It can also be pointed out that physical properties of the PT-1-5% component, deviating from those of the

**Figure 15.** The average NO*<sup>x</sup>* emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels

140 CO2 emissions (Fig. 19) and fuel consumption (Fig. 20) in the NEDC was only slightly higher – in the range of measurement uncertainty – for oxygenated fuel. 20 40

> PT-6- 5%

ON I PT-1- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

3.3.5. CO2 emissions and fuel consumption

measurement uncertainty – for oxygenated fuel.

individual oxygenates at a concentration of 5% v/v

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 18. The average PM emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Glycol ethers, which for the previously analyzed exhaust gas components cause the most favorable changes, were less effective for PM emissions. The greatest reduction in PM emissions was obtained for carbonates and for maleates. The use of *n*-butanol resulted in the lowest reduction in PM emissions of the tested fuels with oxygenated compounds.

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

concentration of 5% v/v

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

PM [g/km]

PM [g/km]

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 17. PM emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

**Figure 19.** The average CO2 emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v Figure 19. The average CO2 emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Figure 20. The average fuel consumption in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing **Figure 20.** The average fuel consumption in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a concentration of 5% v/v

### 3.3.6. A summary of preliminary results *3.3.6. A summary of preliminary results*


> PT-1- 5%

PT-2- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

PT-9- 5%

Figure 21. The percentage change in CO emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5% PT-11- 5% PT-12- 5%

individual oxygenates at a concentration of 5% v/v

Figures 21–24 show the percentage changes in exhaust emissions of the test vehicle in the NEDC by using fuels containing individual oxygenates at a concentration of 5% v/v. The results indicate that some of the oxygenated fuels caused a reduction of CO and HC, and all the fuel types tested caused a reduction of emissions of PM and an increase in NOx emissions. Figures 21–24 show the percentage changes in exhaust emissions of the test vehicle in the NEDC by using fuels containing individual oxygenates at a concentration of 5% v/v. The results indicate that some of the oxygenated fuels caused a reduction of CO and HC, and all the fuel types tested caused a reduction of emissions of PM and an increase in NO*x* emissions.


individual oxygenates at a concentration of 5% v/v

0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,0 4,5 5,0

NOx emissions.

G [dm3/100km]

ON I PT-1- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

3.3.6. A summary of preliminary results

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 20. The average fuel consumption in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Figures 21–24 show the percentage changes in exhaust emissions of the test vehicle in the NEDC by using fuels containing individual oxygenates at a concentration of 5% v/v. The results indicate that some of the oxygenated fuels

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

concentration of 5% v/v

0,000 0,002 0,004 0,006 0,008 0,010 0,012 0,014 0,016 0,018

> > 0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,0 4,5 5,0

NOx emissions.

Change in CO emissions [%]

PT-1- 5%

PT-2- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

PT-9- 5%

Figure 21. The percentage change in CO emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5% PT-11- 5%

PT-12- 5%

G [dm3/100km]

ON I PT-1- 5%

*3.3.6. A summary of preliminary results*

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

fuels containing individual oxygenates at a concentration of 5% v/v

3.3.6. A summary of preliminary results

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 20.** The average fuel consumption in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated

Figures 21–24 show the percentage changes in exhaust emissions of the test vehicle in the NEDC by using fuels containing individual oxygenates at a concentration of 5% v/v. The results indicate that some of the oxygenated fuels caused a reduction of CO and HC, and all the fuel

It should be emphasized that the scale of emission changes of individual exhaust components caused by the different oxygenated fuels varied. It was generally found that fuels containing oxygenated compounds from the group of glycol ethers resulted in the largest, of up to 40%, reduction in emissions of CO and HC with an increase of several percent in NO*x* emission and a moderate reduction of PM emission. Fuels containing carbonates provided the greatest, even by more than 30%, reduction in PM emissions; however, they also increased the emissions of other toxic components of exhaust gases. The advantages of fuels containing maleates were no increase in NO*<sup>x</sup>* and PM reduction greater than when using glycol ethers, although using maleates increased emissions of CO and HC. The effect of oxygenated fuel containing *n*-

types tested caused a reduction of emissions of PM and an increase in NO*x* emissions.

PT-7- 5%

PT-8- 5%

Figure 20. The average fuel consumption in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Figures 21–24 show the percentage changes in exhaust emissions of the test vehicle in the NEDC by using fuels containing individual oxygenates at a concentration of 5% v/v. The results indicate that some of the oxygenated fuels caused a reduction of CO and HC, and all the fuel types tested caused a reduction of emissions of PM and an increase in

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

CO2 [g/km]

ON I PT-1- 5%

64 Alternative Fuels, Technical and Environmental Conditions

PM [g/km]

ON I PT-1- 5%

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

3.3.5. CO2 emissions and fuel consumption

measurement uncertainty – for oxygenated fuel.

PT-2- 5%

individual oxygenates at a concentration of 5% v/v

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

**Figure 19.** The average CO2 emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels

PT-7- 5%

containing individual oxygenates at a concentration of 5% v/v Figure 19. The average CO2 emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

PT-8- 5%

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 18. The average PM emissions in the NEDC (UDC + EUDC) for conventional diesel fuels and oxygenated fuels containing

Glycol ethers, which for the previously analyzed exhaust gas components cause the most favorable changes, were less effective for PM emissions. The greatest reduction in PM emissions was obtained for carbonates and for maleates. The use of *n*-butanol resulted in the lowest reduction in PM emissions of the tested fuels with oxygenated compounds.

CO2 emissions (Fig. 19) and fuel consumption (Fig. 20) in the NEDC was only slightly higher – in the range of

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

PM [g/km]

ON I PT-1- 5%

PT-2- 5%

PT-3- 5%

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

Figure 17. PM emissions during the EUDC for conventional diesel fuels and oxygenated fuels containing individual oxygenates at a

PT-9- 5%

PT-10-5%

PT-11-5%

PT-12-5% ON II

Figure 21. The percentage change in CO emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel **Figure 21.** The percentage change in CO emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐ vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

Figure 22. The percentage change in HC emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel **Figure 22.** The percentage change in HC emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐ vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

butanol on the exhaust emissions is rated as unfavorable, because it resulted in a significant increase in CO emissions at a much lower decrease in PM emissions than for other fuels used. 9 10 

The literature on the influence of oxygenates on the PM emissions for CI engines contains diverging opinions on whether the reduction in PM emissions depends only on the amount of oxygen introduced to the fuel [21, 26, 32, 33], or also on the type of the oxygenated com‐ pound, which is to be used [17, 23, 27, 29]. This divergence of opinion is based on the fact that very few papers [14, 24] present the results of using a wide variety of oxygenates under identical measurement conditions. Comparison of the change of PM emissions in the NEDC shown in Fig. 25 to the oxygen content in the individual oxygenated fuels indicates that 1% of the oxygen contained in the fuel corresponds in most of the cases to a reduction in emissions 0 1 2 3 4 5 6 7 8 Change in NOx emissions [%]

> PT-6- 5%

PT-7- 5%

PT-8- 5%

PT-9- 5%

Figure 23. The percentage change in NOx emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5% PT-11- 5%

PT-12- 5%

PT-1- 5%


Change in PM emissions [%]

PT-1- 5%

PT-2- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-5- 5%

PT-6- 5%

PT-7- 5%

PT-8- 5%

PT-9- 5%

Figure 24. The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5% PT-11- 5% PT-12- 5%

PT-2- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-5- 5%

PT-1- 5%

PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

PT-6- 5%

PT-6- 5%

PT-7- 5%

PT-7- 5%

PT-8- 5%

PT-8- 5%

PT-9- 5%

PT-9- 5%

PT-10- 5%

PT-10- 5%

5%

Figure 24. The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

5%

5%

PT-11- 5%

PT-11- 5%

PT-12- 5%

PT-12- 5%



Change in HC emissions [%]

Change in HC emissions [%]

Figure 23. The percentage change in NOx emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel **Figure 23.** The percentage change in NO*<sup>x</sup>* emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐ vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel Figure 23. The percentage change in NOx emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

Figure 24. The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel **Figure 24.** The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐ vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

of PM in the NEDC by 7–10%. It can be concluded that the oxygen content of fuel is a very important, but not the only, parameter determining the level of reduction of PM emissions. at a concentration of 5% v/v with respect to regular diesel fuel

In assessing the impact of individual oxygenates on the exhaust emission, what should be taken into account, first of all, are the changes in the emission of PM and NO*x*, including the mutual relation of these changes (i.e. PM/NO*<sup>x</sup>* trade-off), due to the fact that they are, on the one hand, the most harmful components, and on the other, the most difficult to remove from the exhaust gas. The effect on emissions of CO and HC should only be taken into account in the longer term, particularly if the impact is significant. On this basis, six oxygenates (shown in the Table 6), which resulted in the most favorable changes in exhaust emissions during preliminary tests described in this chapter, were selected for further, more detailed studies.

It should be emphasized that the scale of emission changes of individual exhaust components caused by the different oxygenated fuels varied. It was generally found that fuels containing oxygenated compounds from the group of glycol ethers resulted in the largest, of up to 40%, reduction in emissions of CO and HC with an increase of several percent in NOx emission and a moderate reduction of PM emission. Fuels containing carbonates provided the greatest, even by more than 30%, reduction in PM emissions; however, they also increased the emissions of other toxic components of exhaust gases. The advantages of fuels containing maleates were no increase in NOx and PM reduction greater than when using glycol ethers, although using maleates increased emissions of CO and HC. The effect of oxygenated fuel containing *n*-butanol on the exhaust emissions is rated as unfavorable, because it resulted in a significant increase in CO

The literature on the influence of oxygenates on the PM emissions for CI engines contains diverging opinions on whether the reduction in PM emissions depends only on the amount of oxygen introduced to the fuel [21, 26, 32, 33], or also on the type of the oxygenated compound, which is to be used [17, 23, 27, 29]. This divergence of opinion is based on the fact that very few papers [14, 24] present the results of using a wide variety of oxygenates under identical measurement conditions. Comparison of the change of PM emissions in the NEDC shown in Fig. 25 to the oxygen content in the individual oxygenated fuels indicates that 1% of the oxygen contained in the fuel corresponds in most of the cases to a

emissions at a much lower decrease in PM emissions than for other fuels used.

Figure 25. The relative effect of oxygen compounds and oxygen content of the fuel on PM emissions in the NEDC **Figure 25.** The relative effect of oxygen compounds and oxygen content of the fuel on PM emissions in the NEDC


**Table 6.** Oxygen compounds selected for further, more detailed analysis 4 Tetraethylene glycol dimethyl ether

of PM in the NEDC by 7–10%. It can be concluded that the oxygen content of fuel is a very important, but not the only, parameter determining the level of reduction of PM emissions.

**Figure 24.** The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐

PT-6- 5%

PT-6- 5%

PT-7- 5%

PT-7- 5%

PT-8- 5%

PT-8- 5%

PT-9- 5%

PT-9- 5%

Figure 24. The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

Figure 24. The percentage change in PM emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5%

PT-10- 5%

PT-11- 5%

PT-11- 5%

PT-12- 5%

PT-12- 5%





Change in PM emissions [%]

Change in PM emissions [%]

PT-1- 5%

PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

at a concentration of 5% v/v with respect to regular diesel fuel

vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

Change in NOx emissions [%]

Change in NOx emissions [%]

PT-1- 5%

PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

at a concentration of 5% v/v with respect to regular diesel fuel

vidual oxygenates at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

PT-6- 5%

PT-6- 5%

**Figure 23.** The percentage change in NO*<sup>x</sup>* emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing indi‐

PT-7- 5%

PT-7- 5%

PT-8- 5%

PT-8- 5%

PT-9- 5%

PT-9- 5%

Figure 23. The percentage change in NOx emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

Figure 23. The percentage change in NOx emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5%

PT-10- 5%

PT-11- 5%

PT-11- 5%

PT-12- 5%

PT-12- 5%

Change in HC emissions [%]

Change in HC emissions [%]

PT-1- 5%

66 Alternative Fuels, Technical and Environmental Conditions

PT-1- 5%

PT-2- 5%

PT-2- 5%

PT-3- 5%

PT-3- 5%

at a concentration of 5% v/v with respect to regular diesel fuel

at a concentration of 5% v/v with respect to regular diesel fuel

PT-4- 5%

PT-4- 5%

PT-5- 5%

PT-5- 5%

PT-6- 5%

PT-6- 5%

PT-7- 5%

PT-7- 5%

PT-8- 5%

PT-8- 5%

PT-9- 5%

PT-9- 5%

Figure 22. The percentage change in HC emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

Figure 22. The percentage change in HC emissions in the NEDC (UDC + EUDC) for oxygenated fuels containing individual oxygenates

PT-10- 5%

PT-10- 5%

PT-11- 5%

PT-11- 5%

PT-12- 5%

PT-12- 5%

In assessing the impact of individual oxygenates on the exhaust emission, what should be taken into account, first of all, are the changes in the emission of PM and NO*x*, including the mutual relation of these changes (i.e. PM/NO*<sup>x</sup>* trade-off), due to the fact that they are, on the one hand, the most harmful components, and on the other, the most difficult to remove from the exhaust gas. The effect on emissions of CO and HC should only be taken into account in the longer term, particularly if the impact is significant. On this basis, six oxygenates (shown in the Table 6), which resulted in the most favorable changes in exhaust emissions during preliminary tests described in this chapter, were selected for further, more detailed studies.

#### **3.4. Evaluation of the impact of oxygenated compounds based on their content in the fuel** 6 Dipropylene glycol dimethyl ether

5 Diethylene glycol dibutyl ether

8 Diethyl maleate

The relationship between the changes in emissions and the content of oxygenated compounds in the fuel is a key issue from the point of view of rational use of oxygenates. Recognition of these relationships also provides additional data for the analysis of the mechanisms of the effect of oxygenates on emissions of toxic exhaust components. The literature reports on the relationship between PM emissions and the oxygen content in the fuel, which is usually defined as approximately linear [20, 26]. Figure 26 shows the results of the influence of the six selected oxygenates used at concentrations of 5 and 10% v/v on the change in emissions of CO, HC, NO*x*, and PM in the NEDC. 11 Diethyl carbonate Table 7. Oxygen compounds selected for further, more detailed analysis

Analyzing these results reveals different impacts of fuels containing components from different chemical groups. In particular, the different impact on emissions between fuels containing glycol ethers (components 3–6), maleates, or carbonates (components 8 and 11).

to 10% produced clearly beneficial effects.

**Figure 26.** The impact of oxygenate content on the change in exhaust emissions over the NEDC

In the case of glycol ethers, it can generally be said that the amount of oxygenated compounds, and thus the amount of oxygen in the fuel, affects PM emissions the most. The reduction of this emission is generally proportional to the content of the oxygenated component/oxygen. Doubling the content of components 3, 4, and 6 resulted in twice the reduction in PM emissions. Increasing the content of the oxygenated components also resulted in the reduction of NO*<sup>x</sup>* emission compared to fuels containing a smaller amount of the oxygenate. Taking into account the PM/NO*x* relationship, an increase in the levels of these oxygenated components from 5 to 10% produced clearly beneficial effects. cause a significant reduction in PM emissions. At 5% content, the glycol ethers were clearly less effective in reducing PM emission than diethyl maleate, and diethyl carbonate. At 10% content, the efficiency of the best components from all tested chemical groups was similar – PM reduction of 30–40%. For most of these fuels, favorable NO*x* emission values at a higher content of oxygenated component were also reported. In relation to CO and HC, it can be generally stated that the oxygenated compounds from the group of glycol ethers were effective in reducing CO and HC emissions in NEDC, while increasing the concentration of the individual oxygenates caused various effects. For component 3, a significant reduction in HC emissions at the same level of CO emission (Fig. 26a) was achieved. For component 4, CO emission was decreased by an additional 8 percentage points, with the same level of HC emission (Fig. 26b). For component 5, CO emission was reduced by a few extra percentage points (Fig. 26c), while increasing emissions of HC in a similar range. For component 6, an increase in CO and HC emissions was reported (Fig. 26d) at higher concentrations of

**Figure 26.** The impact of oxygenate content on the change in exhaust emissions over the NEDC

For fuels containing components 8 and 11, doubling the oxygenated component content in the fuel did not

For fuels containing components 8 and 11, doubling the oxygenated component content in the fuel did not cause a significant reduction in PM emissions. At 5% content, the glycol ethers were clearly less effective in reducing PM emission than diethyl maleate and diethyl carbonate. At 10% content, the efficiency of the best components from all tested chemical groups was similar – PM reduction of 30–40%. For most of these fuels, favorable NO*<sup>x</sup>* emission values at a higher content of oxygenated component were also reported. oxygenated components. Emissions of CO and HC for fuels containing components 8 and 11 (Fig. 26e and f) were clearly higher than for neat diesel, and increasing the oxygen content of the fuel greatly increased this unfavorable phenomenon. For a content of 10% of the oxygenated components 8 and 11, CO and HC emissions were over 100% higher than for neat diesel. In the light of these results, it can be concluded that the use of oxygenated components in the concentration of 10% is preferred, especially for components 3 and 4, where the higher content in the fuel meant significantly lower emissions of PM, and the same or more favorable emission levels of other toxic exhaust components as for the 5% content.

22

In relation to CO and HC, it can be generally stated that the oxygenated compounds from the group of glycol ethers were effective in reducing CO and HC emissions in NEDC, while increasing the concentration of the individual oxygenates caused various effects. For compo‐ nent 3, a significant reduction in HC emissions at the same level of CO emission (Fig. 26a) was achieved. For component 4, CO emission was decreased by an additional 8 percentage points, with the same level of HC emission (Fig. 26b). For component 5, CO emission was reduced by a few extra percentage points (Fig. 26c), while increasing emissions of HC in a similar range. For component 6, an increase in CO and HC emissions was reported (Fig. 26d) at higher concentrations of oxygenated components.

Emissions of CO and HC for fuels containing components 8 and 11 (Fig. 26e and f) were clearly higher than for neat diesel, and increasing the oxygen content of the fuel greatly increased this unfavorable phenomenon. For a content of 10% of the oxygenated components 8 and 11, CO and HC emissions were over 100% higher than for neat diesel.

In the light of these results, it can be concluded that the use of oxygenated components in the concentration of 10% is preferred especially for components 3 and 4, where the higher content in the fuel meant significantly lower emissions of PM, and the same or more favorable emission levels of other toxic exhaust components as for the 5% content.

### **3.5. The effect of oxygenates on exhaust emissions in the conditions of different test cycles**

The level of exhaust emissions for a vehicle of given emission class largely depends on the operating conditions of its engine, in particular parameters such as speed, load, thermal state, as well as the dynamics of changes in these operating conditions. To assess the impact of engine operating conditions on the reduction in exhaust emissions as a result of addition of oxygen‐ ated compounds, the previously performed emission tests in the NEDC regime were followed up with the same type of research carried out for the FTP-75 cycle. Despite being the most widely used worldwide cycles in research of exhaust emissions, the conditions of performing these two cycles are significantly different. Both drive cycles are described in more detail in Section 3.2, but at this point, it should be emphasized that the FTP-75 cycle is more dynamic than NEDC. It is characterized by a more aggressive acceleration, smaller share of engine idling and maximum speed for the cycle (which is slightly lower than for the NEDC) reached in its early stages already.

In the case of glycol ethers, it can generally be said that the amount of oxygenated compounds, and thus the amount of oxygen in the fuel, affects PM emissions the most. The reduction of this emission is generally proportional to the content of the oxygenated component/oxygen. Doubling the content of components 3, 4, and 6 resulted in twice the reduction in PM emissions. Increasing the content of the oxygenated components also resulted in the reduction of NO*<sup>x</sup>* emission compared to fuels containing a smaller amount of the oxygenate. Taking into account the PM/NO*x* relationship, an increase in the levels of these oxygenated components from 5 to

favorable NO*x* emission values at a higher content of oxygenated component were also reported.

**Figure 26.** The impact of oxygenate content on the change in exhaust emissions over the NEDC

For fuels containing components 8 and 11, doubling the oxygenated component content in the fuel did not cause a significant reduction in PM emissions. At 5% content, the glycol ethers were clearly less effective in reducing PM emission than diethyl maleate, and diethyl carbonate. At 10% content, the efficiency of the best components from all tested chemical groups was similar – PM reduction of 30–40%. For most of these fuels,

In relation to CO and HC, it can be generally stated that the oxygenated compounds from the group of glycol ethers were effective in reducing CO and HC emissions in NEDC, while increasing the concentration of the individual oxygenates caused various effects. For component 3, a significant reduction in HC emissions at the same level of CO emission (Fig. 26a) was achieved. For component 4, CO emission was decreased by an additional 8 percentage points, with the same level of HC emission (Fig. 26b). For component 5, CO emission was reduced by a few extra percentage points (Fig. 26c), while increasing emissions of HC in a similar range. For component 6, an increase in CO and HC emissions was reported (Fig. 26d) at higher concentrations of

**– 5% – 10% Figure 26.** The impact of oxygenate content on the change in exhaust emissions over the NEDC

Taking into account the PM/NO*x* relationship, an increase in the levels of these oxygenated components from 5



**Change in emissions [%]**

**Change in emissions [%]**

**Change in emissions [%]**

**CO HC NOx PM**

**b) Oxygenate No. 4**

**d) Oxygenate No. 6**

**f) Oxygenate No. 11**

**CO HC NOx PM**

**CO HC NOx PM**

For fuels containing components 8 and 11, doubling the oxygenated component content in the fuel did not cause a significant reduction in PM emissions. At 5% content, the glycol ethers were clearly less effective in reducing PM emission than diethyl maleate and diethyl carbonate. At 10% content, the efficiency of the best components from all tested chemical groups was similar – PM reduction of 30–40%. For most of these fuels, favorable NO*<sup>x</sup>* emission values at a

Emissions of CO and HC for fuels containing components 8 and 11 (Fig. 26e and f) were clearly higher than for neat diesel, and increasing the oxygen content of the fuel greatly increased this unfavorable phenomenon. For a content of 10% of the oxygenated components 8 and 11, CO and HC emissions were over 100% higher than

In the light of these results, it can be concluded that the use of oxygenated components in the concentration of 10% is preferred, especially for components 3 and 4, where the higher content in the fuel meant significantly lower emissions of PM, and the same or more favorable emission levels of other toxic exhaust components as for

22

10% produced clearly beneficial effects.

oxygenated components.

for neat diesel.

the 5% content.

to 10% produced clearly beneficial effects.

68 Alternative Fuels, Technical and Environmental Conditions

**CO HC NOx PM**

**a) Oxygenate No. 3** 

**c) Oxygenate No. 5**

**e) Oxygenate No. 8**

**CO HC NOx PM**

**CO HC NOx PM**


> -50 -40 -30 -20 -10 0 10

**Change in emissions [%]**

**Change in emissions [%]**

**Change in emissions [%]**

higher content of oxygenated component were also reported.

Figure 27 shows, as an example of the tests performed, a comparison of the results of meas‐ urements of exhaust emissions in the individual phases and the average over the FTP-75 cycle for the test vehicle powered by diesel fuel and oxygenated fuel PT-3-10%. It can be seen that the high CO emission occurs only in the first phase of the FTP-75 cycle. In further phases, the engine thermal condition is stabilized, and the emission significantly reduced. HC emissions are also highest in the first phase, but the decrease in emissions in subsequent phases is not as significant as for CO. This can be related to different efficiencies of catalytic converter in relation to CO and HC emission reduction. It should be pointed out that the exhaust gas temperature in the different phases of the FTP-75 cycle was lower than in the EUDC phase of the NEDC. NO*<sup>x</sup>* emissions during all phases reached similar values, while for PM emissions,

**Figure 27.** Exhaust emissions in the various phases and the average over the FTP-75 cycle for the test vehicle powered by diesel fuel and oxygenated fuel PT-3-10% **Figure 27.** Exhaust emissions in the various phases and the average over the FTP-75 cycle for the test vehicle powered by diesel fuel and oxygenated fuel PT-3-10%

there is a clear dependence on the thermal state and the engine load in the different phases of the FTP-75 cycle. 0 10 -10 0 10 

Figure 28a–f compares the change in exhaust emissions over the NEDC and FTP-75 test cycles as a result of application of oxygenated fuels: PT-3-10%, PT-4-10%, PT-5-10%, PT-6-10-%, PT-8-10%, and PT-11-10%, respectively. Analysis of the results indicates that when there was a significant change in emissions (over 10%), then the direction of emission changes caused by the use of the oxygenated fuel was the same for both test cycles. For most oxygenated fuels, a similar scale of changes in CO and HC emissions was achieved in both test cycles. Changes in NO*<sup>x</sup>* emissions for all oxygenated fuels in both cycles were small – less than 10%. Thus, only PM emissions can point to a clear link between the level of emission changes caused by the use of oxygenated fuels and the conditions of the test cycle. For all the examined oxygenated fuels, and for most significantly, a greater reduction in PM emissions was achieved in the NEDC than the FTP-75 cycle conditions. Larger maximum load on the engine found in the EUDC phase is thought to have been a significant factor. -40 -30 -20 -10 **CO HC NOx PM Change in emissions [%]a) Oxygenated fuel PT-3-10%**  -60 -50 -40 -30 -20 **CO HC NOx PM Change in emissions [%]b) Oxygenated fuel PT-4-10%** -40 -30 -20 -10 0 10 20 **Change in emissions [%]** -20 -10 0 10 20 30 **Change in emissions [%]**

#### **4. Conclusions c) Oxygenated fuel PT-5-10%**


**CO HC NOx PM**

**1.** The use of oxygenated fuels has a significant impact on the level of exhaust emissions from diesel engines without particulate filters. This effect is significant even at low oxygenate content in the fuel (5% v/v).


**CO HC NOx PM**

**d) Oxygenated fuel PT6-10%**

23

**Figure 27.** Exhaust emissions in the various phases and the average over the FTP-75 cycle for the test vehicle powered by The Study on the Influence of Diesel Fuel Oxygenates on Exhaust Emissions http://dx.doi.org/10.5772/62005 71

diesel fuel and oxygenated fuel PT-3-10%

there is a clear dependence on the thermal state and the engine load in the different phases of

**Figure 27.** Exhaust emissions in the various phases and the average over the FTP-75 cycle for the test vehicle powered

**– ON II – PT-3-10% Figure 27.** Exhaust emissions in the various phases and the average over the FTP-75 cycle for the test vehicle powered by diesel fuel and oxygenated fuel PT-3-10%

0,00 0,01 0,02 0,03 0,04 0,05

0,000 0,005 0,010 0,015 0,020 0,025 0,030

**PM [g/mile]**

**HC [g/mile]**

**Phase I Phase II Phase III FTP-75**

**Phase I Phase II Phase III FTP-75**

**CO HC NOx PM**

**CO HC NOx PM**

**d) Oxygenated fuel PT6-10%**

**b) Oxygenated fuel PT-4-10%**

Figure 28a–f compares the change in exhaust emissions over the NEDC and FTP-75 test cycles as a result of application of oxygenated fuels: PT-3-10%, PT-4-10%, PT-5-10%, PT-6-10-%, PT-8-10%, and PT-11-10%, respectively. Analysis of the results indicates that when there was a significant change in emissions (over 10%), then the direction of emission changes caused by the use of the oxygenated fuel was the same for both test cycles. For most oxygenated fuels, a similar scale of changes in CO and HC emissions was achieved in both test cycles. Changes in NO*<sup>x</sup>* emissions for all oxygenated fuels in both cycles were small – less than 10%. Thus, only PM emissions can point to a clear link between the level of emission changes caused by the use of oxygenated fuels and the conditions of the test cycle. For all the examined oxygenated fuels, and for most significantly, a greater reduction in PM emissions was achieved in the NEDC than the FTP-75 cycle conditions. Larger maximum load on the engine found in the

**Change in emissions [%]**


> -40 -30 -20 -10 0 10 20 30

**Change in emissions [%]**

**1.** The use of oxygenated fuels has a significant impact on the level of exhaust emissions from diesel engines without particulate filters. This effect is significant even at low

23

EUDC phase is thought to have been a significant factor.

**c) Oxygenated fuel PT-5-10%**

**CO HC NOx PM**

**CO HC NOx PM**

**a) Oxygenated fuel PT-3-10%** 

oxygenate content in the fuel (5% v/v).

the FTP-75 cycle.

**Change in emissions [%]**

0,00 0,05 0,10 0,15 0,20 0,25

70 Alternative Fuels, Technical and Environmental Conditions

0,0 0,1 0,2 0,3 0,4 0,5 0,6 0,7 0,8

by diesel fuel and oxygenated fuel PT-3-10%


**NOx [g/mile]**

**CO [g/mile]**

**Phase I Phase II Phase III FTP-75**

**Phase I Phase II Phase III FTP-75**

**4. Conclusions**


**Change in emissions [%]**

**Figure 28.** Comparison of changes in exhaust emissions as a result of application of oxygenated fuels over the NEDC and the FTP-75 cycle conditions Figure 28a–f compares the change in exhaust emissions over the NEDC and FTP-75 test cycles as a result of **Figure 28.** Comparison of changes in exhaust emissions as a result of application of oxygenated fuels over the NEDC and the FTP-75 cycle conditions


Fuels containing glycol ethers cause a reduction of CO and HC emission, while fuels containing maleates, carbonates or butanol cause its growth.


### **Author details**

Miłosław Kozak\*

Address all correspondence to: Miloslaw.Kozak@put.poznan.pl

Poznań University of Technology, Poznań, Poland

### **References**


[6] Merkisz J., Kozak M.: Internal Combustion Engines at the Beginning of the Third Millennium. International Scientific Conference: Development of Design of Internal Combustion Engines and Quality of Fuels to Meet Future Levels, Kraków 20-21.06.2011.

Fuels containing glycol ethers cause a reduction of CO and HC emission, while fuels

**5.** Increasing the concentration of oxygenates in the fuel from 5 to 10% v/v causes different effects for different components. The most favorable changes in emissions were observed for glycol ethers – where increased concentration was usually followed by a further significant reduction in PM emissions, and, to a lesser extent, reductions in CO and HC emissions. For maleates and carbonates, changes were less favorable, because a slight decrease in PM emissions was accompanied by a significant increase in CO and HC

**6.** The effect of the test conditions (NEDC/ FTP-75 cycle) on changes in exhaust emissions occur primarily for PM – where a greater reduction was achieved in the NEDC. Changes

**7.** The slight increase in NO*x* emissions and substantially lower PM emissions associated with the use of oxygenated fuels should be judged as a favorable change in the correlation of PM/NOx emissions (the PM/NOx trade-off). In this situation, there is a possibility for reducing the exhaust emissions of both aforementioned components at the same time.

[1] European Environment Agency, www.eea.europa.eu, access on 15 June 2015.

[2] United States Environmental Protection Agency (EPA): Health Assessment Docu‐

[3] European Automobile Manufacturers' Association (ACEA), www.acea.be, access on

[4] Główny Urząd Statystyczny: Gospodarka paliwowo-energetyczna w latach 2011, 2012, Warszawa 2013 (*Polish Central Statistic Office: Energy Statistics 2011, 2012, War‐*

[5] Benazzi E.: Gasoline and Diesel Imbalances in the Atlantic Basin. Petroleum Technol‐

containing maleates, carbonates or butanol cause its growth.

72 Alternative Fuels, Technical and Environmental Conditions

in NO*x* emissions for all fuels in both cycles do not exceed 10%.

Address all correspondence to: Miloslaw.Kozak@put.poznan.pl

ment For Diesel Engine Exhaust, Waszyngton, 2002.

Poznań University of Technology, Poznań, Poland

emissions.

**Author details**

Miłosław Kozak\*

**References**

15 June 2015.

*saw 2013*).

ogy Quarterly, nr 2/2011.


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