**Author details**

Bahareh Bahramian\* and Fariba Dehghani

\*Address all correspondence to: fariba.dehghani@sydney.edu.au

School of Chemical & Biomolecular Engineering, University of Sydney, Sydney, Australia

## **References**


**Author details**

Bahareh Bahramian\*

**References**

j.cattod.2006.02.029

10.1002/biot.201000134

views. 2008; 48: pp. 192–219

220 DOI: 10.1002/macp.1969.021300112

ronmental. 2010; 98: pp. 101–111

and Fariba Dehghani

84 Advanced Catalytic Materials - Photocatalysis and Other Current Trends

\*Address all correspondence to: fariba.dehghani@sydney.edu.au

School of Chemical & Biomolecular Engineering, University of Sydney, Sydney, Australia

[1] Song C: Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemi‐ cal processing. Catalysis Today. 2006; 115: pp. 2–32 DOI: http://dx.doi.org/10.1016/

[2] Zhong X, Dehghani F: Solvent free synthesis of organometallic catalysts for the co‐ polymerization of carbon dioxide and propylene oxide. Applied Catalysis B: Envi‐

[3] Qin Y, Wang X: Carbon dioxide-based copolymers: Environmental benefits of PPC, an industrially viable catalyst. Biotechnology Journal. 2010; 5: pp. 1164–1180 DOI:

[4] Sakakura T, Choi J-C, Yasuda H: Transformation of carbon dioxide. Chemical Re‐

[5] Luinstra G A: Poly(propylene carbonate), old copolymers of propylene oxide and carbon dioxide with new interests: Catalysis and material properties. Polymer Re‐

[6] Inoue S, Koinuma H, Tsuruta T: Copolymerization of carbon dioxide and epoxide with organometallic compounds. Die Makromolekulare Chemie. 1969; 130: pp. 210–

[7] Ree M, Bae J Y, Jung J H, Shin T J, Hwang Y T, Chang T: Copolymerization of carbon dioxide and propylene oxide using various zinc glutarate derivatives as catalysts.

[8] Kim J S, Ree M, Shin T J, Han O H, Cho S J, Hwang Y T, Bae J Y, Lee J M, Ryoo R, Kim H: X-ray absorption and NMR spectroscopic investigations of zinc glutarates prepared from various zinc sources and their catalytic activities in the copolymerization of carbon

[9] Meng Y Z, Du L C, Tiong S C, Zhu Q, Hay A S: Effects of the structure and morphology of zinc glutarate on the fixation of carbon dioxide into polymer. Journal of Polymer

dioxide and propylene oxide. Journal of Catalysis. 2003; 218: pp. 209–219

views. 2007; 107: pp. 2365–2387 DOI: 10.1021/cr068357u

Polymer Engineering and Science. 2000; 40: pp. 1542–1552

Science, Part A: Polymer Chemistry. 2002; 40: pp. 3579–3591


lysts. Die Makromolekulare Chemie. 1977; 178: pp. 2149–2158 DOI: 10.1002/macp. 1977.021780802


epoxide. Journal of the American Chemical Society. 1986; 108: pp. 391–395 DOI: 10.1021/ja00263a008

[35] Chen P, Chisholm M H, Gallucci J C, Zhang X, Zhou Z: Binding of propylene oxide to porphyrin− and salen−M(III) cations, where M = Al, Ga, Cr, and Co. Inorganic Chemistry. 2005; 44: pp. 2588–2595 DOI: 10.1021/ic048597x

lysts. Die Makromolekulare Chemie. 1977; 178: pp. 2149–2158 DOI: 10.1002/macp.

[24] Kuran W, Pasynkiewicz S, Skupińska J, Rokicki A: Alternating copolymerization of carbon dioxide and propylene oxide in the presence of organometallic catalysts. Die Makromolekulare Chemie. 1976; 177: pp. 11–20 DOI: 10.1002/macp.1976.021770102 [25] Soga K, Uenishi K, Hosoda S, Ikeda S: Copolymerization of carbon dioxide and pro‐ pylene oxide with new catalysts. Die Makromolekulare Chemie. 1977; 178: pp. 893–

[26] Soga K, Uenishi K, Ikeda S: Homopolymerization of propylene oxide and copolymer‐ ization of propylene oxide and carbon dioxide with metal salts of acetic acid. Journal of Polymer Science: Polymer Chemistry Edition. 1979; 17: pp. 415–423 DOI: 10.1002/

[27] Soga K, Imai E, Hattori I: Alternating copolymerization of CO2 and propylene oxide with the catalysts prepared from Zn(OH)<sup>2</sup> and various dicarboxylic acids. Polymer

[28] Pescarmona P P, Taherimehr M: Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2. Catalysis Science & Technology. 2012;

[29] Moore D R, Cheng M, Lobkovsky E B, Coates G W: Mechanism of the alternating co‐ polymerization of epoxides and CO2 using β-diiminate zinc catalysts:  Evidence for a bimetallic epoxide enchainment. Journal of the American Chemical Society. 2003;

[30] Laugel G, Rocha C C, Massiani P, Onfroy T, Launay F: Homogeneous and heteroge‐ neous catalysis for the synthesis of cyclic and polymeric carbonates from CO2 and ep‐ oxides: A mechanistic overview. Advanced Chemistry Letters. 2013; 1: pp. 195–214

[31] Aida T, Ishikawa M, Inoue S: Alternating copolymerization of carbon dioxide and epoxide catalyzed by the aluminum porphyrin-quaternary organic salt or triphenyl‐ phosphine system. Synthesis of polycarbonate with well-controlled molecular

[32] Kruper W J, Dellar D D: Catalytic Formation of cyclic carbonates from epoxides and CO2 with chromium metalloporphyrinates. The Journal of Organic Chemistry. 1995;

[33] Aida T, Inoue S: Catalytic reaction on both sides of a metalloporphyrin plane. Alter‐ nating copolymerization of phthalic anhydride and epoxypropane with an alumi‐ num porphyrin-quaternary salt system. Journal of the American Chemical Society.

[34] Kojima F, Aida T, Inoue S: Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of a carbamic ester from carbon dioxide, amine, and

weight. Macromolecules. 1986; 19: pp. 8–13 DOI: 10.1021/ma00155a002

Journal. 1981; 13: pp. 407–410 DOI: 10.1295/polymj.13.407

1977.021780802

pol.1979.170170211

897 DOI: 10.1002/macp.1977.021780325

86 Advanced Catalytic Materials - Photocatalysis and Other Current Trends

2: pp. 2169–2187 DOI: 10.1039/c2cy20365k

125: pp. 11911–11924 DOI: 10.1021/ja030085e

60: pp. 725–727 DOI: 10.1021/jo00108a042

1985; 107: pp. 1358–1364 DOI: 10.1021/ja00291a041

DOI: 10.1166/acl.2013.1036


phenoxides for the copolymerization of epoxides and carbon dioxide. Journal of the American Chemical Society. 1999; 121: pp. 107–116 DOI: 10.1021/ja9826284


[55] Eberhardt R, Allmendinger M, Rieger B: DMAP/Cr(III) Catalyst ratio: The decisive factor for poly(propylene carbonate) formation in the coupling of CO2 and propylene oxide. Macromolecular Rapid Communications. 2003; 24: pp. 194–196 DOI: 10.1002/ marc.200390022

phenoxides for the copolymerization of epoxides and carbon dioxide. Journal of the

American Chemical Society. 1999; 121: pp. 107–116 DOI: 10.1021/ja9826284

3229–3238 DOI: 10.1021/ja003851f

88 Advanced Catalytic Materials - Photocatalysis and Other Current Trends

pp. 6494–6504

2010.12.002

ja012714v

126: pp. 11404–11405 DOI: 10.1021/ja0472580

1268 DOI: http://dx.doi.org/10.1016/j.ccr.2005.01.023

125: pp. 7586–7591 DOI: 10.1021/ja034863e

[45] Chamberlain B M, Cheng M, Moore D R, Ovitt T M, Lobkovsky E B, Coates G W: Polymerization of lactide with zinc and magnesium β-diiminate complexes:  Stereo‐ control and mechanism. Journal of the American Chemical Society. 2001; 123: pp.

[46] Byrne C M, Allen S D, Lobkovsky E B, Coates G W: Alternating copolymerization of limonene oxide and carbon dioxide. Journal of the American Chemical Society. 2004;

[47] Allen S D, Moore D R, Lobkovsky E B, Coates G W: High-activity, single-site cata‐ lysts for the alternating copolymerization of CO2 and propylene oxide. Journal of the

[48] Chisholm M H, Navarro-Llobet D, Zhou Z: Poly(propylene carbonate). 1. More about poly(propylene carbonate) formed from the copolymerization of propylene oxide and carbon dioxide employing a zinc glutarate catalyst. Macromolecules. 2002; 35:

[49] Venkataramanan N S, Kuppuraj G, Rajagopal S: Metal–salen complexes as efficient catalysts for the oxygenation of heteroatom containing organic compounds—synthet‐ ic and mechanistic aspects. Coordination Chemistry Reviews. 2005; 249: pp. 1249–

[50] Martinez L E, Leighton J L, Carsten D H, Jacobsen E N: Highly enantioselective ring opening of epoxides catalyzed by (salen)Cr(III) complexes. Journal of the American

[51] Klaus S, Lehenmeier M W, Anderson C E, Rieger B: Recent advances in CO2/epoxide copolymerization—New strategies and cooperative mechanisms. Coordination Chemistry Reviews. 2011; 255: pp. 1460–1479 DOI: http://dx.doi.org/10.1016/j.ccr.

[52] Jacobsen E N: Asymmetric catalysis of epoxide ring-opening reactions. Accounts of

[53] Darensbourg D J, Yarbrough J C: Mechanistic aspects of the copolymerization reac‐ tion of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst. Journal of the American Chemical Society. 2002; 124: pp. 6335–6342 DOI: 10.1021/

[54] Darensbourg D J, Yarbrough J C, Ortiz C, Fang C C: Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copoly‐ mer vs cyclic carbonate production. Journal of the American Chemical Society. 2003;

Chemical Society. 1995; 117: pp. 5897–5898 DOI: 10.1021/ja00126a048

Chemical Research. 2000; 33: pp. 421–431 DOI: 10.1021/ar960061v

American Chemical Society. 2002; 124: p. 14284-14285 DOI: 10.1021/ja028071g


[75] Quan Z, Wang X, Zhao X, Wang F: Copolymerization of CO2 and propylene oxide under rare earth ternary catalyst: design of ligand in yttrium complex. Polymer. 2003; 44: pp. 5605–5610 DOI: http://dx.doi.org/10.1016/S0032-3861(03)00561-5

[65] Chen L-B: Activation and copolymerization of CO2 by macromolecule-metal com‐ plexes. Makromolekulare Chemie. Macromolecular Symposia. 1992; 59: pp. 75–82

[66] Kim I, Yi M J, Byun S H, Park D W, Kim B U, Ha C S: Biodegradable polycarbonate synthesis by copolymerization of carbon dioxide with epoxides using a heterogene‐ ous zinc complex. Macromolecular Symposia. 2005; 224: pp. 181–192 DOI: 10.1002/

[67] Kim I, Yi M J, Lee K J, Park D-W, Kim B U, Ha C-S: Aliphatic polycarbonate synthesis by copolymerization of carbon dioxide with epoxides over double metal cyanide cat‐ alysts prepared by using ZnX2 (X = F, Cl, Br, I). Catalysis Today. 2006; 111: pp. 292–

[68] Darensbourg D J, Adams M J, Yarbrough J C: Toward the design of double metal cy‐ anides for the copolymerization of CO2 and epoxides. Inorganic Chemistry. 2001; 40:

[69] Robertson N J, Qin Z, Dallinger G C, Lobkovsky E B, Lee S, Coates G W: Two-dimen‐ sional double metal cyanide complexes: highly active catalysts for the homopolyme‐ rization of propylene oxide and copolymerization of propylene oxide and carbon

[70] Chen S, Hua Z, Fang Z, Qi G: Copolymerization of carbon dioxide and propylene ox‐ ide with highly effective zinc hexacyanocobaltate(III)-based coordination catalyst. Polymer. 2004; 45: pp. 6519–6524 DOI: http://dx.doi.org/10.1016/j.polymer.

[71] Chen X, Shen Z, Zhang Y: New catalytic systems for the fixation of carbon dioxide. 1. Copolymerization of carbon dioxide and propylene oxide with new rare-earth cata‐ lysts-RE(P204)3-Al(i-Bu)3-R(OH)n. Macromolecules. 1991; 24: pp. 5305–5308 DOI:

[72] Shen Z, Chen X, Zhang Y: New catalytic systems for the fixation of carbon dioxide, 2. Synthesis of high molecular weight epichlorohydrin/carbon dioxide copolymer with rare earth phosphonates/triisobutyl-aluminium systems. Macromolecular Chemistry

[73] Guo J-T, Wang X-Y, Xu Y-S, Sun J-W: Copolymerizations of carbon dioxide and ep‐ oxides in the presence of rare earth coordinate catalyst. Journal of Applied Polymer

[74] Liu B, Zhao X, Wang X, Wang F: Copolymerization of carbon dioxide and propylene oxide with neodymium trichloroacetate-based coordination catalyst. Polymer. 2003;

and Physics. 1994; 195: pp. 2003–2011 DOI: 10.1002/macp.1994.021950610

44: pp. 1803–1808 DOI: http://dx.doi.org/10.1016/S0032-3861(03)00034-X

Science. 2003; 87: pp. 2356–2359 DOI: 10.1002/app.11923

296 DOI: http://dx.doi.org/10.1016/j.cattod.2005.10.039

dioxide. Dalton Transactions. 2006; 45: pp. 5390–5395

pp. 6543–6544 DOI: 10.1021/ic0155941

DOI: 10.1002/masy.19920590108

90 Advanced Catalytic Materials - Photocatalysis and Other Current Trends

masy.200550616

2004.07.044

10.1021/ma00019a014


[101] Williams C, Kember M, Buchard A,Jutz F, Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent, 2013, Google Patents

[87] Alvaro M, Baleizao C, Carbonell E, El Ghoul M, García H, Gigante B: Polymer-bound aluminium salen complex as reusable catalysts for CO2 insertion into epoxides. Tetra‐ hedron. 2005; 61: pp. 12131–12139 DOI: http://dx.doi.org/10.1016/j.tet.2005.07.114

[88] Alvaro M, Baleizao C, Das D, Carbonell E, García H: CO2 fixation using recoverable chromium salen catalysts: use of ionic liquids as cosolvent or high-surface-area sili‐ cates as supports. Journal of Catalysis. 2004; 228: pp. 254–258 DOI: http://dx.doi.org/

[89] Shohei I, Hideomi K, Teiji T: Process for producing copolymer of epoxide and carbon

[90] Shohei I, Masaki K, Nobuyuki M, Tadamichi T, Masanori Y, Catalyst for copolymer‐

[91] Sun H, Soluble epoxide/carbon dioxide copolymerization catalysts, 1988, Google Pat‐

[92] Kawachi H, Minami S, Armor J N, Rokicki A, Stein B K, Zinc-containing solid cata‐ lyst, process of preparing same and process for preparing polyalkylene carbonate,

[93] Motika S A, Pickering T L, Rokicki A, Stein B K, Catalyst for the copolymerization of

[94] Kogut S, Rom C, Schimmel K H, Wagenknecht E, Catalyst system for producing pol‐

[95] Jong-Sung K, Kie-Soo K, Seung-Jae M, Moon-Hor R, Method of preparing catalyst for polymerization of aliphatic polycarbonate and method of polymerizing aliphatic pol‐

[96] Döring M P D, Kröger M D, New substituted N-phenyl-3-phenylaminoacrylimidate zinc complexes useful as catalysts, especially for polycarbonate production by reac‐

[97] Bohres E, Heinemann J, Luinstra G, Verfahren zur herstellung aliphatischer polycar‐

[98] Coates G, Qin Z, Cohen C, Polycarbonates made using highly selective catalysts,

[99] Williams C K, Kember M, Knight P, Bimetallic catalytic complexes for the copoly‐

[100] Klein J, Kragl U, Kunze C, Marquardt M, Paetzold E, Zander L, Katalysator zur epox‐ idpolymerization und zur copolymerization von epoxid mit kohlendioxid, 2012,

merization of carbon dioxide and an epoxide, 2009, Google Patents

izing epoxy compounds with carbon dioxide, 1975, Google Patents

10.1016/j.jcat.2004.08.022

1991, Google Patents

epoxides with CO2, 1991, Google Patents

yalkylene carbonates, 1999, Google Patents

ycarbonate using same, 2003, Google Patents

bonate, 2003, Google Patents

2006, Google Patents

Google Patents

tion of epoxides with carbon dioxide, 2005, Google Patents

ents

dioxide, 1971, Google Patents

92 Advanced Catalytic Materials - Photocatalysis and Other Current Trends

[102] Rokicki A, Making poly(alkylene carbonates) of controlled molecular weight, 1990, Google Patents
