**Abstract**

The offshore Nile Delta basin is considered as one of the most promising province in Egypt which has an excellent potential gas and condensate reserves for future exploration. This study aimed to characterize the origin of natural gas and to determine whether it is biogenic, thermogenic or mixed processes which are consid‐ ered the dominant generation pathways. Regional geochemical studies were conducted on 20 test gas samples produced from the Miocene and Plio-Pleistocene reservoirs of Abu Qir, N. Abu Qir, Temsah, Wakkar and Port Fouad fields represent‐ ing the western and the eastern Nile Delta province. The geochemical analyses revealed that the main constituents of the natural gases are methane (96.2%–99.37%) with minor contribution from ethane and propane. Methane carbon isotopic compo‐ sition ranges between \_ 65.6‰ and \_ 40.3 ‰ PDB displaying a strong indication for gas mixing of thermogenic and early microbial methane. The gas chromatography\_mass spectrometry carried out on the produced natural gases exhibits high oleanane index that ranges between 19% and 42%, the medium concentration of moretane index between 11% and 16% and the absence of gammacerane index indicating that the natural gases were derived from siliciclastic source rocks containing type III kerogen of terrestrial origin and higher land plants input of Tertiary age. The calculated maturity parameters of the studied natural gas proportions based on various sterane isomerisation distributions, i.e. C29αßß/(αßß+ααα)\_and C29ααα20S/(S+R) reached 0.6 and 0.5 respectively indicating a medium stage of thermal maturation equivalent to the main peak of oil generation window (0.85 Ro%). The sterane isomerization ratios may reflect the rapid rate of subsidence and sedimentation in the Nile Delta and appear to have been generated during the early stage of source rock maturation.

**Keywords:** biogenic, thermogenic, Nile Delta, biomarkers, Egypt

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