**5. Microstructure of AM Ti-6Al-4V (As built)**

### **5.1. Microstructure of SLS Ti-6Al-4V**

SLS is largely similar to the conventional PM and this explains that the microstructure of SLS Ti-6Al-4V is close to that of equilibrium state as with the PM or cast Ti-6Al-4V [79-88]. Figure 8 compares the microstructure of SLS Ti-6Al-4V with that of an HIP Ti-6Al-4V [81]. In general both materials are of lamellar structure consisting of (α+β) phases and show no evident difference to each other.

**Figure 8.** Optical microscopy images of (a) an HIP Ti-6Al-4V and (b) an SLS then HIP Ti-6Al-4V. The latter generally presents a lamellar type of microstructure and almost identical to the former [81].

#### **5.2. Microstructure of EBM, SLM and SMD Ti-6Al-4V**

#### *5.2.1. Solidification map*

As aforementioned, regarding EBM, SLM and SMD, the AM processing is essentially a solidification process [29-78]. In this regard, the solidification map (see Fig. 9) suggested by Kobryn and Semiatin [1] is useful for predicting the solidification microstructure and can even be served for microstructural design. The two parameters, *R* and *G*, that are crucial for composing the solidification map can be measured and/or calculated as follows:

An Overview of Densification, Microstructure and Mechanical Property of Additively Manufactured Ti-6Al-4V… http://dx.doi.org/10.5772/59275 87

$$R = \text{ d}z/\text{d}t\tag{1}$$

$$\mathbf{G} = \mathbf{d}T/\mathbf{dz} \tag{2}$$

where *R* is the solidification velocity which can be calculated based on a distance (d*z*) moved by solidus isotherm over a certain amount of time (d*t*), and *G* is the thermal gradient which can be obtained using a temperature window (d*T*) between solidus and liquids isotherms over a certain amount of distance (d*z*).

**Figure 9.** Solidification map of Ti-6Al-4V with simulated laser-glaze data points [1].

#### *5.2.2. Texture and heterogeneity issue*

the SLS. Indeed, for these three laser-based processing approaches, the densification process is more of solidification from liquid rather than the normal sense of sintering. The so-called time-temperature-transformation (T-T-T) of Ti-6Al-4V regulates phase selection and phase constitution of the solidified microstructure. Figure 7 provides the T-T-T curve of the Ti-6Al-4V alloy containing different levels of oxygen [91]. Under equilibrium conditions (i.e. low cooling rates), the resultant microstructure will be a mixture of thermodynamically stable α and β

SLS is largely similar to the conventional PM and this explains that the microstructure of SLS Ti-6Al-4V is close to that of equilibrium state as with the PM or cast Ti-6Al-4V [79-88]. Figure 8 compares the microstructure of SLS Ti-6Al-4V with that of an HIP Ti-6Al-4V [81]. In general both materials are of lamellar structure consisting of (α+β) phases and show no evident

**Figure 8.** Optical microscopy images of (a) an HIP Ti-6Al-4V and (b) an SLS then HIP Ti-6Al-4V. The latter generally

As aforementioned, regarding EBM, SLM and SMD, the AM processing is essentially a solidification process [29-78]. In this regard, the solidification map (see Fig. 9) suggested by Kobryn and Semiatin [1] is useful for predicting the solidification microstructure and can even be served for microstructural design. The two parameters, *R* and *G*, that are crucial for

composing the solidification map can be measured and/or calculated as follows:

presents a lamellar type of microstructure and almost identical to the former [81].

**5.2. Microstructure of EBM, SLM and SMD Ti-6Al-4V**

phases, while high cooling rates can enable formation of martensite phases.

**5. Microstructure of AM Ti-6Al-4V (As built)**

**5.1. Microstructure of SLS Ti-6Al-4V**

difference to each other.

86 Sintering Techniques of Materials

*5.2.1. Solidification map*

Texture and heterogeneity are widely observable microstructural features in EBM, SLM and SMD Ti-6Al-4V [29-76]. They are formed mainly due to the following two reasons: (a) different temperature distribution in the as-built sample and (b) different cooling rates in the various parts of the sample.

Figure 10 provides optical graphs for an EBM Ti-6Al-4V at the transverse direction (Fig. 10a) and longitudinal direction (Fig. 10b) [4]. The former shows a lamellar microstructure while the later presents directional growth along the build direction. Greater thermal gradient in the latter is suggested to be the main reason for the formation of this columnar type of micro‐ structure [4]. Figure 11 shows other two examples to illustrate the microstructural heteroge‐ neity between the surface (Fig. 11a) and the bulk material (Fig. 11b) [71]. In this case, the much faster cooling rate in the surface of the AM Ti-6Al-4V has contributed to the formation of the acicular, metastable martensite phases in Fig. 11(a) while the bulk material presents a bimodal, equilibrium microstructure due to a much lower cooling rate, see Fig.11(b).

Figure 10 Optical microscopy images of the EBM Ti-6Al-4V from the (a) transverse cross-section and (b) longitudinal cross-section. Build direction is given in (b). Texture/directional growth can be found in (b) [4]. **Figure 10.** Optical microscopy images of the EBM Ti-6Al-4V from the (a) transverse cross-section and (b) longitudinal cross-section. Build direction is given in (b). Texture/directional growth can be found in (b) [4].

**5.2.3 Martensite phase transformation**  Cooling rate of SLM, EBM and LMD can be 104 K/s - 106 **Figure 11.** SEM images of the LMD Ti-6Al-4V which show heterogeneity among (a) the surface of the alloy (lamellar with martensite phases) and (b) base/bulk material [71].

K/s high [29-76]. This enables martensite

#### phases to form in the microstructure. Figure 12 proposes the dependency of phase selection on the cooling rate for Ti-6Al-4V [92,93]. Acicular α̍, massive martensite αm or equilibrium (α+β) is *5.2.3. Martensite phase transformation*

proposed for each representative cooling rate. A minimum cooling rate of 20°C/s is suggested to be necessary for the formation of the martensite phases while when cooling rate is higher than 525°C/s the entire microstructure can be featured as acicular α̍ martensite. One still needs to note that the real cooling rate during AM processing of Ti-6Al-4V, other materials as well, is still a research question to be further investigated. Figure 13 provides an example from an EBM Ti-6Al-4V where featherless α̍ can be found in the microstructure [94]. The stable α phase is also observable in the microstructure although it is suggested that the cooling rate during EBM can be much higher than the critical cooling rate for the martensite phase transformation and accordingly the microstructure should have been overwhelmingly martensite. This is not consistent with the microstructural observation. Cooling rate of SLM, EBM and LMD can be 104 K/s-106 K/s high [29-76]. This enables martensite phases to form in the microstructure. Figure 12 proposes the dependency of phase selection on the cooling rate for Ti-6Al-4V [92,93]. Acicular α, massive martensite αm or equilibrium (α +β) is proposed for each representative cooling rate. A minimum cooling rate of 20°C/s is suggested to be necessary for the formation of the martensite phases while when cooling rate is higher than 525°C/s the entire microstructure can be featured as acicular α martensite. One still needs to note that the real cooling rate during AM processing of Ti-6Al-4V, other materials as well, is still a research question to be further investigated. Figure 13 provides an example from an EBM Ti-6Al-4V where featherless α can be found in the microstructure [94]. The stable

10

α phase is also observable in the microstructure although it is suggested that the cooling rate during EBM can be much higher than the critical cooling rate for the martensite phase transformation and accordingly the microstructure should have been overwhelmingly martensite. This is not consistent with the microstructural observation.

acicular, metastable martensite phases in Fig. 11(a) while the bulk material presents a bimodal,

Figure 10 Optical microscopy images of the EBM Ti-6Al-4V from the (a) transverse cross-section and (b) longitudinal cross-section. Build direction is given in (b). Texture/directional growth can be found in (b) [4].

**Figure 10.** Optical microscopy images of the EBM Ti-6Al-4V from the (a) transverse cross-section and (b) longitudinal

**Build direction**

Figure 11 SEM images of the LMD Ti-6Al-4V which show heterogeneity among (a) the surface of the alloy (lamellar with martensite phases) and (b) base/bulk material [71].

K/s - 106

K/s-106

phases to form in the microstructure. Figure 12 proposes the dependency of phase selection on the cooling rate for Ti-6Al-4V [92,93]. Acicular α̍, massive martensite αm or equilibrium (α+β) is proposed for each representative cooling rate. A minimum cooling rate of 20°C/s is suggested to be necessary for the formation of the martensite phases while when cooling rate is higher than 525°C/s the entire microstructure can be featured as acicular α̍ martensite. One still needs to note that the real cooling rate during AM processing of Ti-6Al-4V, other materials as well, is still a research question to be further investigated. Figure 13 provides an example from an EBM Ti-6Al-4V where featherless α̍ can be found in the microstructure [94]. The stable α phase is also observable in the microstructure although it is suggested that the cooling rate during EBM can be much higher than the critical cooling rate for the martensite phase transformation and accordingly the microstructure should have been

phases to form in the microstructure. Figure 12 proposes the dependency of phase selection on the cooling rate for Ti-6Al-4V [92,93]. Acicular α, massive martensite αm or equilibrium (α +β) is proposed for each representative cooling rate. A minimum cooling rate of 20°C/s is suggested to be necessary for the formation of the martensite phases while when cooling rate is higher than 525°C/s the entire microstructure can be featured as acicular α martensite. One still needs to note that the real cooling rate during AM processing of Ti-6Al-4V, other materials as well, is still a research question to be further investigated. Figure 13 provides an example from an EBM Ti-6Al-4V where featherless α can be found in the microstructure [94]. The stable

**Figure 11.** SEM images of the LMD Ti-6Al-4V which show heterogeneity among (a) the surface of the alloy (lamellar

overwhelmingly martensite. This is not consistent with the microstructural observation.

K/s high [29-76]. This enables martensite

K/s high [29-76]. This enables martensite

**5.2.3 Martensite phase transformation**  Cooling rate of SLM, EBM and LMD can be 104

Cooling rate of SLM, EBM and LMD can be 104

with martensite phases) and (b) base/bulk material [71].

*5.2.3. Martensite phase transformation*

10

equilibrium microstructure due to a much lower cooling rate, see Fig.11(b).

88 Sintering Techniques of Materials

cross-section. Build direction is given in (b). Texture/directional growth can be found in (b) [4].

**Figure 12.** Schematic graph to show the relationship between phase selection and cooling rate during solidification (from 1050°C). The initial state of the Ti-6Al-4V alloy is as β phase [92,93].

**Figure 13.** Electron beam scattered diffraction (EBSD) image to show the featureless α' martensite phase and the sur‐ rounding microstructure of an EBM Ti-6Al-4V [94].
