**8. References**


As an example, Table A1 lists the parameters of equation for calculating the uncertainties of the enthalpies of vaporization caused by errors of the vapor pressures for some freons.

*RC* and .2/

*Hs m T* )}({ , J·mol-1

*T* )}({ values by

)/(5.0)/({ <sup>2</sup>

3

<sup>2</sup> 10}/){ *<sup>m</sup> Hs <sup>m</sup> <sup>H</sup>* , %

2/1] <sup>2</sup> }2

*D R*

2/ ,/) <sup>2</sup>

*TTB <sup>H</sup>* ,/ <sup>2</sup>

*T*

CFCl2CFCl2 2.306 0.389 0.0104 339 0.66 56918 337.6 43.1 0.12 CF2ClCFCl2 2.775 114 21.64 308 - - - 130.6 0.45 CF2BrCF2Br 2.569 27.8 3.709 310 - - - 60.2 0.21

<sup>1</sup> *Hs <sup>m</sup>* /()}({ *molJT KTgedcKTbat KT* (A22)

for freons CFCl2CFCl2, CF2ClCFCl2 and CF2BrCF2Br at *<sup>T</sup>* = 298.15 K, where 05.0*<sup>t</sup>* denotes the

This equation was obtained by summing up dispersions of the orthogonal coefficients of equation (A19). Errors of the *Hm T* )( *vap* values caused by uncertainties of *pT* data equal

Adachi K.; Suga H. & Seki S. (1968). Phase changes in crystalline and glassy-crystalline

Alexandrov, Yu.I. (1975). *Tochnaja Kriometrija Organicheskih Veschestv* (Exact criometric of

Boublik, T.; Fried, V. & Hala, E. (1984). *The vapour pressure of pure substances*, Elsevier, ISBN

Chikos, J.S. & Acree Jr., W.E. (2003). Enthalpies of vaporization of organic and

Cohen, N. & Benson, S.W*.* (1993). Estimation of Heat of Formation of Organic Compounds by Additivity Methods. *Chemical Reviews*. Vol. 93, (1993), p.p. 2419-2438 Domalski, E.S. & Hearing, E.D. (1993). Estimation of the Thermodynamic Properties of C-H-

Emel'yanenko, V.N.; Verevkin, S.P.; Krol, O.V.; Varushchenko, R.M. & Chelovskaya, N.V.

Emel'yanenko, V.N.; Krol, O.V.; Varushchenko, R.M.; Druzhinina, A.I. & Verevkin, S.P.

cyclohexanol. *Bulletin Chemical Society of Japan,* 41, No 5, (May 1968), p.p.1073-1087,

organometallic compounds. *Journal of Physical and Chemical Reference Data,* Vol. 32,

N-O-S-Halogen Compounds at 298.15 K. *Journal of Physical and Chemical Reference* 

(2007). Vapour pressures and enthalpies of vaporization of a series of the ferrocene derivatives. *Journal of Chemical Thermodynamics.*, Vol. 39, No 4, (April 2007), p.p.

(2010). The Termodynamic Characteristics of Ferrocene Alkyl and Acyl Derivatives.

}/{([ 05.0 )

<sup>32</sup> ( *<sup>R</sup>*

Compounds 05.0*<sup>t</sup> <sup>a</sup> <sup>b</sup> <sup>c</sup>* <sup>3</sup> <sup>10</sup> *<sup>d</sup> <sup>e</sup> <sup>g</sup>*

Table A1. Parameters of equation for calculation of the *Hs m*

to those of the direct calorimetric methods (Table 2).

organic substances)*.* Khimiya, Leningrad

*Data,* Vol. 22, No 4, p.p. 805-1159, ISSN 0047-2689

 

Student criterion.

**8. References** 

ISSN 0009-2673

0-444-41097-X, Amsterdam

594-601, ISSN 0021-9614

No 2, p.p. 519-878, ISSN 0047-2689

*Russian Journal of Physical Chemistry A.* Vol. 84, No 7, (July 2010), p.p. 1089-1097, ISSN 0036-0244


**23** 

**Thermodynamics and Thermokinetics to** 

**Temperature and Pressure Ranges Under** 

Hirohisa Yoshida3, Jean-Marc Haudin4 and Jean-Loup Chenot4

*4MINES ParisTech, CEMEF, UMR CNRS 7635, Sophia Antipolis* 

*1Institut P PRIME-P', ISAE-ENSMA, UPR CNRS 3346, Futuroscope Chasseneuil 2Université Blaise Pascal de Clermont-Ferrand, Laboratoire de Thermodynamique,* 

*3Tokyo Metropolitan University, Faculty of Urban Environmental Science, Tokyo* 

A scientific understanding of the behaviour of polymers under extreme conditions of temperature and pressure becomes inevitably of the utmost importance when the objective is to produce materials with well-defined final in-use properties and to prevent the damage of materials during on-duty conditions. The proper properties as well as the observed damages are related to the phase transitions together with intimate pattern organization of

Thermodynamic and thermokinetic issues directly result from the thermodynamic independent variables as temperature, pressure and volume that can stay constant or be scanned as a function of time. Concomitantly, these variables can be coupled with a mechanical stress, the diffusion of a solvent, and/or a chemically reactive environment. A mechanical stress can be illustrated in a chemically inert environment by an elongation and/or a shear. Diffusion is typically described by the sorption of a solvent. A chemical environment is illustrated by the presence of a reactive environment as carbon dioxide or

Challenging aspects are polymer pattern multi scale organizations, from the nanometric to the macrometric scale, and their importance regarding industrial and technological problems, as described in the state of the art in Part 2. New horizons and opportunities are at hands through pertinent approaches, including advanced *ad hoc* experimental techniques with improved modelling and simulation. Four striking illustrations, from the interactions

between a solvent and a polymer to the growth patterns, are illustrated in Part 3.

**1. Introduction** 

the materials.

hydrogen for example.

 **Model Phase Transitions of** 

**Polymers over Extended** 

*UMR CNRS 6272, Aubière* 

*1,2,4France 3Japan* 

**Various Hydrostatic Fluids** 

Séverine A.E. Boyer1, Jean-Pierre E. Grolier2,

