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**6** 

*Russia* 

**Advanced Sintering Techniques in** 

**Oxygen Separation Membranes** 

Vladislav Sadykov et al.\*

**Design of Planar IT SOFC and Supported** 

*Boreskov Institute of Catalysis, Novosibirsk State University, Novosibirsk,* 

Thin film solid oxide fuel cells (SOFC) operating in the intermediate temperature (IT) range are now considered as promising for distributed, mobile, standby or auxiliary power generation. At present one of the most important scientific aims in design of solid oxide fuel cells is to lower the operating temperatures to 600-800С. In this temperature range, majority of problems inherent to SOFC operating at high (950-1000C) are alleviated. Thus, cations interdiffusion and solid state reactions between electrolyte and electrodes are hampered and thermal stresses are decreased which prevent degradation of the functional layers [Yamamoto, 2004 ]. Hence, design of thin film SOFC requires also elaboration of nanostructured electrodes compatible with electrolytes from chemical and thermophysical points of view and providing a developed three-phase boundary (TPB). In this respect, broad options are provided by design of nanocomposite mixed ionic-electronic conducting (MIEC)

functional layers – (Sadykov et al., 2010; Sadykov et al., 2009; Sadykov et al., 2008).

One of the most demanding problem in solid oxide fuel cells design is caused by the necessity of co-sintering of thin layers (electrolyte, functionally graded nanocomposite cathode) to provide required density without degradation of their transport, electrochemical and thermo-mechanical properties. The most developed and cost-effective are methods based upon supporting electrolyte powders with addition of organic binders and dispersants via screen-printing (Souza et al., 1998), tape casting (Kobayashi et al., 2002) or slurry coating technique (Jung et al., 2007). Thus supported «green» layers are sintered at

\* Vladimir Usoltsev1, Yulia Fedorova1, Natalia Mezentseva1, Tamara Krieger1, Nikita Eremeev1, Marina Arapova1, Arcady Ishchenko1, Alexey Salanov1, Vitaly Pelipenko1, Vitaly Muzykantov1, Artem Ulikhin2, Nikolai Uvarov2, Oleg Bobrenok3, Alexander Vlasov4, Mikhail Korobeynikov4, Aleksei Bryazgin4,

Andrei Arzhannikov4, Petr Kalinin4, Oleg Smorygo5 and Manfred Thumm6 *1Boreskov Institute of Catalysis, Novosibirsk State University, Novosibirsk, Russia 2Institute of Solid State Chemistry and Mechanochemistry, Novosibirsk, Russia*

*3Institute of Thermal Physics, Novosibirsk, Russia 4Budker Institute of Nuclear Physics, Novosibirsk, Russia*

*5Institute of Powder Metallurgy, Minsk, Belarus 6Karlsruhe Inst. Technology, Karlsruhe, Germany* 

**1. Introduction** 

