**Abstract**

The power demand is increasing day by day owing to the diminishing of fossil fuel reserves on the globe. To overcome the future energy crises, there is a strong need to fulfill the energy loophole by novel technologies such as triboelectric nanogenerators to harvest miniature resources from renewable natural resources. Here, I discussed the synthesis and fabrication of novel triboelectric nanogenerators (TENGs) using highly reproducible power generators as electropositive surfaces from the monomers of naphthalene tetracarboxylic dianhydride, benzdiene diamine, and sulfonated polyimide (Bno-Spi), and modified nonwoven carbon fibers (Wcf) and polytetrafluoroethylene (PTFE) and polyvinylidene difluoride (PVDF) as electronegative TENG electrodes, respectively. Here, novel double characteristic hydrophilic and hydrophobic nano-channels concerned with Bno-Spi films were proposed through contact electrification process through ion and electron transfer by an electron-donor-acceptor complex mechanism. The proposed Bno-Spi-TENG system High triboelectric open circuit voltage 75 V (Voc) and short circuit current 1 μA (Jsc) have been achieved from Bno-Spi-TENGs, in particular, and for SO3H.Bno-Spi-TENG at 6 Hz. Besides that, we used improved knitted woven carbon fiber composite (wcf-COOH), as one of the TENGs to generate a greater open-circuit voltage (V*oc*), and short circuit current (I*sc*). Also, I aimed the contact and separation mode TENG which is using spring structure through oxidation of Wcf into Wcf-COOH followed by coupling of aniline through and one-step oxidative polymerization to get woven carbon fiber-polyaniline emraldine salt (Wcf-Pani.Es). The Wcf-PANI.Es composite film (thickness ~ 100 nm) shows the surface resistivity of 0.324 Ω m, and functions as a rubbing surface to produce charges through harvesting of energy using vertical contact-separation mode TENG. The vibrant exchanges of novel Wcf-Pani.Es, and PVDF membrane produced higher V*oc* of 95 V, and I*sc* of 180 μA, correspondingly. In specific, Wcf-Pani.Es -TENG is shown an enhancement of 498% of V*oc* concerning Wcf-COOH-TENG due to the availability of the Pani.Es layer. The novel Bno-Spi-TENGs and Wcf-Pani.Es are the potential candidates for fulfilling the need for improved energy harvesting devices as an alternate substantial choice for contact-separation mode TENGs.

**Keywords:** triboelectric nanogenerator, contact-electrification, Bno-Spi, Wcf-TENG, ionic electrets
