**2. Phosphate in water bodies**

*Applications of Biochar for Environmental Safety*

oxide through chemical co-precipitation [4].

phsophorus is a non-renewable source available in limited quantities in nature with Morocco owning approximately 75% of the market [3]. There is an uncertainty about the lifetime of the remaining reserves and their accessibility. Studies have shown that P reserves are limited and will deplete soon with the increasing use of phosphorus as a fertilizer for agronomic production. Thus, it is crucial to develop

Many technologies have been studied for phosphate removal from industrial and municipal effluents; these have been categorized into chemical, physical, and biological wastewater treatments. Studies have proven the effectiveness of biological and chemical treatments. These treatment methods use plants such as algae or chemicals such as alum, lime, and ferric salts to remove phosphorus from water before discharge into water bodies. Studies have shown that 97% of the total phosphorus (TP) could be removed from aqueous solutions with the use of phosphate biological treatment methods which does not present the risk of adding chemical contaminants to the water. However, the phosphate removal efficiency may be low due to its sensitivity to operation conditions [1]. However, other treatment method costs remain expensive, and some of them necessitate continuous checking of the operating conditions in order to prevent the introduction of new contaminants into the water. Thus, developing a cost-effective technology to prevent eutrophication and manage phosphorus recovery will prevent the shortage of this important element as it can be recycled and reused if it is successfully recovered from wastewater. Adsorption presents a low-cost and efficient method for phosphorus removal due to its cost-effectiveness, accessibility, and performance. However, the high cost of traditional adsorbents (e.g., active carbon and anion exchange resins) and the difficulty of disposal are problems that limit their use. Thus, researchers study the development possibility of low-cost adsorbents that could come from cheap and available products such as biomass. Biochar has been studied as a prospective adsorbent for its properties including low cost, availability, stability, high porosity, and non-costly preparation and upgrading [2]. However, powder carbon-based biochars were identified to be difficult to separate from aqueous solutions which requires the use of magnetic separation that requires the addition of magnetic iron

Biochar has many advantages over traditional adsorbents such as being environmentally friendly, recyclable, low cost, easy to prepare, and having a high porosity. Consequently, researchers have studied the potential application of biochar as a phosphate adsorbent from wastewater [5] and its use as a fertilizer for soil quality enhancement. However, non-modified biochar with a surface charged negatively has a limited adsorption capacity for anionic pollutants which requires impregnating some metals on the biochar surface (Fe, Mg, Al, etc.) [2]. The preparation process of magnetic adsorbents is considered complicated and costly due to the complicated steps involved starting by the precursor preparation, oxidation of activated carbon, and then iron grafting [6]. For this reason, biochar use as a phosphate adsorbent from wastewater needs to be examined. Factors affecting the effectiveness of the anionic pollutant adsorption such as the functional site amount, affinity, dispersion, and surface accessibility need to be considered [7]. Some researchers studied the phosphate adsorption capacity of modified biochar. Junk et al. prepared magnetic biochar by magnesium ferrite impregnation through co-precipitation of Mg and Fe and pyrolysis and found to have an adsorption capacity of 487.99 mg P/g where P is the symbol of phosphorus [8, 9]. Junk et al. adsorption rate is considered among the highest when compared to other biochars adsorption rates 41.16 mg P/g,

125.40 mg P/g, 135 mg P/g [13, 17, 40]; this is shown later in Section 4 [7].

Other techniques are also employed to improve biochar surface characteristics for better adsorption. These treatment methods can be divided into gas phase

effective phosphate removal technologies from aqueous solution.

**72**

P is a vital nutrient for the growth of aquatic organisms, plants, and animals [12, 13]. It also plays an essential role as a limiting nutrient, preventing the development of algae and aquatic plants in the water ecosystem [14]. TP amount needs to be less than 0.03 mg/L, while phosphate level between 0.005 and 0.05 mg/L as an excessive amount of phosphate in water bodies causes eutrophication. Eutrophication leads to the destruction of water ecosystem including rivers, lakes, and seas causing harm to human health and an increase to the water treatment cost [15]. Natural phosphate reserves are limited and will be depleted in 50–100 years [16]. Thus, phosphorus recovery from phosphate-rich wastewater can simultaneously solve the phosphorus depletion issue and improve water quality [17].

## **3. Biochar production through pyrolysis and hydrothermal carbonization (HTC)**

### **3.1 Biochar production from hydrothermal carbonization**

Biomass HTC is performed at temperatures ranging from 160–800°C. It is categorized into low-temperature reactions (lower than 300°C) and high-temperature reactions (300–800°C). During high-temperature HTC, the principal reaction is gasification, and the products are gases including hydrogen and methane [18] while carbonization takes place at low temperatures. Gasification favors the production of methane and hydrogen through

$$\text{C}\_6\text{H}\_{12}\text{O}\_6 + \text{6H}\_2\text{O} \rightarrow \text{6CO}\_2 + 12\text{H}\_2\tag{1}$$

$$\text{C}\_6\text{H}\_{12}\text{O}\_6 \xrightarrow{} \text{3}\text{CH}\_4 + \text{3CO}\_2 \tag{2}$$

Hydrogen formation is endothermic and methane formation is exothermic. Therefore, at high temperatures hydrogen formation exceeds methane as illustrated in **Figure 1**.

Hydrothermal carbonization is used for high moisture content biomass contrarily to pyrolysis and gasification that deals with low moisture content biomass [19]. Many factors affect the hydrochar characteristics. These include the waterto-biomass ratio, reaction temperature, residence time, and pressure. Hydrochar is defined as the product of HTC reaction and has a 40–70 wt% yield. Hydrochars have lower yields but high higher heating value (HHV) than low-temperature pyrolysis (LTP) pyrochars [20]. The ultimate analysis confirmed these findings as it shows hydrochars having high carbon contents and low oxygen contents than pyrochars. Pyrochars have higher yields than hydrochars and thus higher-energy yields despite their lower HHVs. This indicates that biomass experienced a deep carbonization and decomposition in the LTP process. Oliveira et al. [21] showed that deeper carbonization of biochar can be achieved by combining different

### **Figure 1.**

*Different biomass conversion processes overview and vapor-pressure water curve [18].*

agricultural residues and different types of biomass. The use of lignocellulosic residues leads to hydrochars with high-energy yields.

In addition, hydrochars produced good dewatering and drying properties. The water involved in the process could be reused which will reduce the environmental impact and increase the energy efficiency. Different researchers have studied production conditions such as feedstock, temperature, and residence time on hydrochar. Sabio et al. [22] reported that the main factors affecting the hydrochar solid yield are residence time and temperature. Producing hydrochars in the ideal conditions can contribute to promote energy densification (increase in HHV).

### **3.2 Biochar production from biomass pyrolysis**

Pyrolysis is used for the conversion of biomass into alternative products such as biochar, syngas, and bio-oil in an oxygen-free environment at temperatures ranging from 300 to 900°C. There are different types of reactors used to produce biochar including pyrolysis rotary drums, paddle pyrolysis kiln, and auger reactor [23].

The rotary drum reactor is considered a reliable system for biochar production. The reactor is composed of internal concentric steel tube and a rotary part made of insulated mantle. The mantle supports a sequence of radial steel fins and connects to the steel tube. Two fixed parts at the rotary end are responsible of the charge and the discharge of solid and gaseous products. The biomass moves through the carbonization kiln, passes inside the internal concentric tube, and is moved at increasing temperatures through various sections. The biomass temperature fumes enter the furnace and increase the temperature to 500°C. The carbonization process requires heat that is delivered by burning gases and pyrolysis vapors. The process is energy independent except the starting phase that uses external combustion. Fumes exit the reactor through the chimney while the produced biochar is gathered in a stocking silo [24] (**Figure 2**).

The auger pyrolysis reactor is normally nourished with wood waste by a hopper at the retort end. The wood waste is transported through an auger into other extremities for carbonization. The vapors and gases are sent to a condenser, and

**75**

**Figure 3.** *Auger reactor [24].*

**Figure 2.**

*Pyrolysis rotary drum [24].*

*Comparative Evaluation of Hydrochars and Pyrochars for Phosphate Adsorption from Wastewater*

The paddle pyrolysis reactor is a low-temperature gasifier. Its main characteristics is to move and mix biomass increasing the heat transfer on the material surface. The system output is biochar and syngas; the reactor has a unique cleanup system to

Pyrolysis can be divided into two types, slow and fast pyrolysis, based on the reaction conditions (heating rate, residence time, pressure, and mainly temperature) [25]. Slow pyrolysis is conducted in temperatures ranging from 400 to 600°C and is used in applications that seek a high biochar yield and a low bio-oil and syngas products including CH4, H2, CO, CO2, and C1–C2 hydrocarbons. The reaction is conducted at atmospheric pressure and residence time longer than 1 h at a heating rate in the range of 5–7°C/min [25, 26]. These conditions lead to more cracking reactions which decrease the liquid yield and consequently increase biochar yield [27]. Slow pyrolysis also called conventional carbonization process produces high biochar yields mainly for feedstocks with high ash content, lignin, and particle size [28]. Another factor that can contribute to high biochar yield is the increasing particle size

This is a simple, cost-effective but powerfully built process which is mainly applicable to small-scale biochar production farms. On the other hand, fast pyrolysis has more opportunities toward increasing bio-oil yield up to 75% from original

the biochar is collected in the retort through a single tube. The main structure at the lowest level includes a combustion chamber where carbonization occurs. The

combustion chamber uses gases to provide heat [24] (**Figure 3**).

*DOI: http://dx.doi.org/10.5772/intechopen.92612*

of the sample.

produce syngas for downstream applications [24].

### *Comparative Evaluation of Hydrochars and Pyrochars for Phosphate Adsorption from Wastewater DOI: http://dx.doi.org/10.5772/intechopen.92612*

the biochar is collected in the retort through a single tube. The main structure at the lowest level includes a combustion chamber where carbonization occurs. The combustion chamber uses gases to provide heat [24] (**Figure 3**).

The paddle pyrolysis reactor is a low-temperature gasifier. Its main characteristics is to move and mix biomass increasing the heat transfer on the material surface. The system output is biochar and syngas; the reactor has a unique cleanup system to produce syngas for downstream applications [24].

Pyrolysis can be divided into two types, slow and fast pyrolysis, based on the reaction conditions (heating rate, residence time, pressure, and mainly temperature) [25]. Slow pyrolysis is conducted in temperatures ranging from 400 to 600°C and is used in applications that seek a high biochar yield and a low bio-oil and syngas products including CH4, H2, CO, CO2, and C1–C2 hydrocarbons. The reaction is conducted at atmospheric pressure and residence time longer than 1 h at a heating rate in the range of 5–7°C/min [25, 26]. These conditions lead to more cracking reactions which decrease the liquid yield and consequently increase biochar yield [27]. Slow pyrolysis also called conventional carbonization process produces high biochar yields mainly for feedstocks with high ash content, lignin, and particle size [28]. Another factor that can contribute to high biochar yield is the increasing particle size of the sample.

This is a simple, cost-effective but powerfully built process which is mainly applicable to small-scale biochar production farms. On the other hand, fast pyrolysis has more opportunities toward increasing bio-oil yield up to 75% from original

**Figure 2.** *Pyrolysis rotary drum [24].*

**Figure 3.** *Auger reactor [24].*

*Applications of Biochar for Environmental Safety*

agricultural residues and different types of biomass. The use of lignocellulosic

In addition, hydrochars produced good dewatering and drying properties. The water involved in the process could be reused which will reduce the environmental impact and increase the energy efficiency. Different researchers have studied production conditions such as feedstock, temperature, and residence time on hydrochar. Sabio et al. [22] reported that the main factors affecting the hydrochar solid yield are residence time and temperature. Producing hydrochars in the ideal conditions can contribute to promote energy densification (increase

Pyrolysis is used for the conversion of biomass into alternative products such as biochar, syngas, and bio-oil in an oxygen-free environment at temperatures ranging from 300 to 900°C. There are different types of reactors used to produce biochar including pyrolysis rotary drums, paddle pyrolysis kiln, and auger reactor [23]. The rotary drum reactor is considered a reliable system for biochar production. The reactor is composed of internal concentric steel tube and a rotary part made of insulated mantle. The mantle supports a sequence of radial steel fins and connects to the steel tube. Two fixed parts at the rotary end are responsible of the charge and the discharge of solid and gaseous products. The biomass moves through the carbonization kiln, passes inside the internal concentric tube, and is moved at increasing temperatures through various sections. The biomass temperature fumes enter the furnace and increase the temperature to 500°C. The carbonization process requires heat that is delivered by burning gases and pyrolysis vapors. The process is energy independent except the starting phase that uses external combustion. Fumes exit the reactor through the chimney while the produced biochar is gathered in a

The auger pyrolysis reactor is normally nourished with wood waste by a hopper at the retort end. The wood waste is transported through an auger into other extremities for carbonization. The vapors and gases are sent to a condenser, and

residues leads to hydrochars with high-energy yields.

*Different biomass conversion processes overview and vapor-pressure water curve [18].*

**3.2 Biochar production from biomass pyrolysis**

**74**

stocking silo [24] (**Figure 2**).

in HHV).

**Figure 1.**

raw biomass, and in contrast to slow pyrolysis the heating rate is higher than 200°C/min and residence time less than 10 s which favors the decrease in biochar yield [29].

## **4. Remediation technologies for phosphate removal in aqueous solutions using biochar**

Many researchers have explored different paths for phosphate adsorption from wastewater. Methods have been studied including solvent extraction, chemical precipitation, gravity separation, ion exchange, reverse osmosis, solvent extraction, electrodialysis and electrocoagulation, adsorption, and flotation for phosphate removal from sewage system [30]. Adsorption is preferred for cost-effectiveness. However, waste sludge disposal resulting from adsorption of phosphate from wastewater is complicated and expensive which hinders the use of adsorption technique for phosphate removal in industrial scale.

The use of metal salts has been explored for phosphate removal. Most metals have a strong ability to adsorb contaminants using electrostatic attraction between the surface charged negatively and the metal ions charged positively [31]. Moreover, there is a limitation on transforming agricultural residues to green by-products since most farmers burn their crop stalk causing more greenhouse gas emissions and harm to the environment. Biochar could be used as a clean environmental by-product as it is produced in an oxygen-free environment and can be used for different applications [13]. The use of biochar and impregnation of metal oxides on its surface for phosphate adsorption was studied as a technique for contaminant removal.

Techniques for phosphorus recovery can be categorized as physical (electrodialysis, reverse osmosis, ion exchange) [1], chemical, and biological [32]. Some of the mostly used techniques are ion exchange, chemical precipitation, electrocoagulation, chemical precipitation, crystallization, and adsorption. Phosphorus chemical precipitation can be achieved by the deposition of some metal elements and metal oxides. Crystallization can be represented by attractive struvite (magnesium ammonium phosphate) which is a white crystal containing important elements for the growth of plants. Struvite is composed of Mg, P, and N with equal molar concentrations. Struvite can be crystallized and applied to the soil as a fertilizer or used for the recovery of phosphorus and nitrogen. However, the economic feasibility of struvite precipitation is influenced by the costs of reagents such as magnesium. Magnesium sources such as MgO are environmental materials; their advantage is the high alkalinity than other alkalis. Alkalinity plays an important role in acid neutralization as well as creation of adequate pH region for crystallization. The MgO available in the market is a solid mineral which releases low amounts of Mg due to slow dissolution [33]. Struvite crystallization can be used for sludge anaerobic digestion due to the high concentration of ammonia and phosphorus in reactors. Struvite formation formula is

$$\text{Mg}^{2+} + \text{NH}\_4^+ + \text{PO}\_4^{3-} + \text{6} \text{H}\_2\text{O} \rightarrow \text{MgNH}\_4\text{PO}\_4\text{6} \text{(H}\_2\text{O)}\tag{3}$$

**77**

of the reactions.

*Comparative Evaluation of Hydrochars and Pyrochars for Phosphate Adsorption from Wastewater*

Adsorption is another attractive technology. It has been well-known for its simplicity, low cost, and high adsorption capacity. Different adsorbents have been tested for phosphate adsorption from wastewater including activated carbon, metal-based materials, and designed engineering particles. These adsorbents have shown some drawbacks such as high cost and inefficiency. Thus, increasing interest is going to agricultural by-products. During the past several years, research studies have been done on the removal of contaminants from aqueous solutions using biochar. Biochar is considered a potential great adsorbent because of its high ion exchange capacity, large surface area, and abundant functional groups. However, adsorption of biochar to anion pollutants such as PO43<sup>−</sup> phosphate anion is limited due to the negatively charged surface of biochar and its low anion exchange capacity. Thus, studies suggested that the removal capacity can be improved by using chemical co-precipitation to deposit metal element cations (Ca2+, Fe3+, Al3+, Mg2+) or metal oxides (CaO, MgO, La2O3, Fe2O3, Al2O3). Metal oxides and elements react

Ion exchange is carried to remove certain ions from an aqueous solution. It is used for purification of aqueous solutions with the use of polymeric ion exchange resin or other materials that have ion exchange properties. Ion exchangers can be anion exchangers (exchanging ions charged negatively) or cation exchangers (exchanging ions charged positively). Ion exchange is considered a reversible process where the ion exchanger could be loaded with appropriate ions through washing with these ions excess. Electrostatic attraction is a force that binds particles to non-conducting surfaces. Simple Coulombic attraction helps in the attraction of charged particles to oppositely charged surfaces. However, both surfaces do not

Biochar has been produced from different precursors at different conditions and tested in the laboratory to study its adsorption capacity. In recent years, it has been noticed a growing interest in converting anaerobic digestion residue to biochar [38]. Jiwei et al. [9] produced a MgO-modified biochar using chemical co-precipitation of Mg2+ and Fe3+ on biochar from anaerobic digestion residue. The modified biochar was pyrolyzed at different temperatures and tested for phosphate removal from aqueous solution. The modified biochar reached its maximum phosphate adsorption capacity of 149.25 mg/g. The influence of reaction parameters on adsorption was also investigated, including temperature, solution pH, phosphate concentration, and coexisting anions. Ci et al. [39] used corn biochar with impregnated magnesium for phosphate adsorption. The biochar was pyrolyzed at 300, 450, and 600°C and dipped in MgCl2 and pyrolyzed again under same conditions. The maximum phosphate adsorption using the Langmuir-Freundlich model is 239 mg/g. The biochar produced from anaerobic digested sugar beet tailing has been studied as a phosphate adsorbent from wastewater. Yao et al. [1] indicated that MgO particles present on the biochar surface allow better phosphate ion adsorption of 133.08 mg/g according to the Langmuir model. However, the anaerobic digestion of biochar makes it more costly as anaerobic digestion requires more time and control

Ningyuan et al. [13] prepared a wheat straw biochar impregnated with Bismuth at 400, 500, and 600°C for application in wastewater. The bismuth impregnation increased the specific surface area and micropores which played the role of adsorption sites for phosphorus. Bismuth biochars showed high phosphate sorption ability to phosphate with maximum P adsorption capacity of 125.40 mg/g. Hui et al. [17] prepared a hydrochar composite by hydrothermal carbonization of tobacco stalk. The hydrochar composite was prepared by adding the prepared feedstock to metal solution containing AlCl3 and MgCl2 and then putting the solution in autoclave at 180°C for 12 h. However, the highest P adsorption observed is 41.16 mg P/g at 45°C

need to be charged as particles can be attracted to neutral surfaces [37].

<sup>3</sup><sup>−</sup>, resulting in improved anion removal rate [36].

*DOI: http://dx.doi.org/10.5772/intechopen.92612*

with oxyanions such as PO4

The struvite chemical precipitation has high adsorption of soluble phosphate 80–90% [34]. Struvite precipitation faces challenges in phosphorus recovery from wastewater when the phosphorus concentration is below 50 mg/L and the suspended solid concentration is higher than 2000 mg/L [35]. Mariana et al. [35] suggested the application of struvite precipitation in secondary streams with high phosphorus concentrations.

*Comparative Evaluation of Hydrochars and Pyrochars for Phosphate Adsorption from Wastewater DOI: http://dx.doi.org/10.5772/intechopen.92612*

Adsorption is another attractive technology. It has been well-known for its simplicity, low cost, and high adsorption capacity. Different adsorbents have been tested for phosphate adsorption from wastewater including activated carbon, metal-based materials, and designed engineering particles. These adsorbents have shown some drawbacks such as high cost and inefficiency. Thus, increasing interest is going to agricultural by-products. During the past several years, research studies have been done on the removal of contaminants from aqueous solutions using biochar. Biochar is considered a potential great adsorbent because of its high ion exchange capacity, large surface area, and abundant functional groups. However, adsorption of biochar to anion pollutants such as PO43<sup>−</sup> phosphate anion is limited due to the negatively charged surface of biochar and its low anion exchange capacity. Thus, studies suggested that the removal capacity can be improved by using chemical co-precipitation to deposit metal element cations (Ca2+, Fe3+, Al3+, Mg2+) or metal oxides (CaO, MgO, La2O3, Fe2O3, Al2O3). Metal oxides and elements react with oxyanions such as PO4 <sup>3</sup><sup>−</sup>, resulting in improved anion removal rate [36].

Ion exchange is carried to remove certain ions from an aqueous solution. It is used for purification of aqueous solutions with the use of polymeric ion exchange resin or other materials that have ion exchange properties. Ion exchangers can be anion exchangers (exchanging ions charged negatively) or cation exchangers (exchanging ions charged positively). Ion exchange is considered a reversible process where the ion exchanger could be loaded with appropriate ions through washing with these ions excess. Electrostatic attraction is a force that binds particles to non-conducting surfaces. Simple Coulombic attraction helps in the attraction of charged particles to oppositely charged surfaces. However, both surfaces do not need to be charged as particles can be attracted to neutral surfaces [37].

Biochar has been produced from different precursors at different conditions and tested in the laboratory to study its adsorption capacity. In recent years, it has been noticed a growing interest in converting anaerobic digestion residue to biochar [38]. Jiwei et al. [9] produced a MgO-modified biochar using chemical co-precipitation of Mg2+ and Fe3+ on biochar from anaerobic digestion residue. The modified biochar was pyrolyzed at different temperatures and tested for phosphate removal from aqueous solution. The modified biochar reached its maximum phosphate adsorption capacity of 149.25 mg/g. The influence of reaction parameters on adsorption was also investigated, including temperature, solution pH, phosphate concentration, and coexisting anions. Ci et al. [39] used corn biochar with impregnated magnesium for phosphate adsorption. The biochar was pyrolyzed at 300, 450, and 600°C and dipped in MgCl2 and pyrolyzed again under same conditions. The maximum phosphate adsorption using the Langmuir-Freundlich model is 239 mg/g.

The biochar produced from anaerobic digested sugar beet tailing has been studied as a phosphate adsorbent from wastewater. Yao et al. [1] indicated that MgO particles present on the biochar surface allow better phosphate ion adsorption of 133.08 mg/g according to the Langmuir model. However, the anaerobic digestion of biochar makes it more costly as anaerobic digestion requires more time and control of the reactions.

Ningyuan et al. [13] prepared a wheat straw biochar impregnated with Bismuth at 400, 500, and 600°C for application in wastewater. The bismuth impregnation increased the specific surface area and micropores which played the role of adsorption sites for phosphorus. Bismuth biochars showed high phosphate sorption ability to phosphate with maximum P adsorption capacity of 125.40 mg/g. Hui et al. [17] prepared a hydrochar composite by hydrothermal carbonization of tobacco stalk. The hydrochar composite was prepared by adding the prepared feedstock to metal solution containing AlCl3 and MgCl2 and then putting the solution in autoclave at 180°C for 12 h. However, the highest P adsorption observed is 41.16 mg P/g at 45°C

*Applications of Biochar for Environmental Safety*

for phosphate removal in industrial scale.

reactors. Struvite formation formula is

phosphorus concentrations.

*Mg*2+ + *NH*<sup>4</sup>

<sup>+</sup> + *PO*<sup>4</sup>

The struvite chemical precipitation has high adsorption of soluble phosphate 80–90% [34]. Struvite precipitation faces challenges in phosphorus recovery from wastewater when the phosphorus concentration is below 50 mg/L and the suspended solid concentration is higher than 2000 mg/L [35]. Mariana et al. [35] suggested the application of struvite precipitation in secondary streams with high

yield [29].

removal.

**using biochar**

raw biomass, and in contrast to slow pyrolysis the heating rate is higher than 200°C/min and residence time less than 10 s which favors the decrease in biochar

**4. Remediation technologies for phosphate removal in aqueous solutions** 

Many researchers have explored different paths for phosphate adsorption from wastewater. Methods have been studied including solvent extraction, chemical precipitation, gravity separation, ion exchange, reverse osmosis, solvent extraction, electrodialysis and electrocoagulation, adsorption, and flotation for phosphate removal from sewage system [30]. Adsorption is preferred for cost-effectiveness. However, waste sludge disposal resulting from adsorption of phosphate from wastewater is complicated and expensive which hinders the use of adsorption technique

The use of metal salts has been explored for phosphate removal. Most metals have a strong ability to adsorb contaminants using electrostatic attraction between the surface charged negatively and the metal ions charged positively [31]. Moreover, there is a limitation on transforming agricultural residues to green by-products since most farmers burn their crop stalk causing more greenhouse gas emissions and harm to the environment. Biochar could be used as a clean environmental by-product as it is produced in an oxygen-free environment and can be used for different applications [13]. The use of biochar and impregnation of metal oxides on its surface for phosphate adsorption was studied as a technique for contaminant

Techniques for phosphorus recovery can be categorized as physical (electrodialysis, reverse osmosis, ion exchange) [1], chemical, and biological [32]. Some of the mostly used techniques are ion exchange, chemical precipitation, electrocoagulation, chemical precipitation, crystallization, and adsorption. Phosphorus chemical precipitation can be achieved by the deposition of some metal elements and metal oxides. Crystallization can be represented by attractive struvite (magnesium ammonium phosphate) which is a white crystal containing important elements for the growth of plants. Struvite is composed of Mg, P, and N with equal molar concentrations. Struvite can be crystallized and applied to the soil as a fertilizer or used for the recovery of phosphorus and nitrogen. However, the economic feasibility of struvite precipitation is influenced by the costs of reagents such as magnesium. Magnesium sources such as MgO are environmental materials; their advantage is the high alkalinity than other alkalis. Alkalinity plays an important role in acid neutralization as well as creation of adequate pH region for crystallization. The MgO available in the market is a solid mineral which releases low amounts of Mg due to slow dissolution [33]. Struvite crystallization can be used for sludge anaerobic digestion due to the high concentration of ammonia and phosphorus in

3− + 6 *H*2*O* → *MgNH*4 *PO*<sup>4</sup> 6(*H*2*O*) (3)

**76**

adsorption reaction time. Ming et al. [40] produced a biochar composite material which linked biochar with AlOOH nanoparticles. The biochar was produced through a slow pyrolysis of AlCl3 <sup>−</sup> pretreated biomass at 600°C. The characterization of the AlOOH biochar showed a uniform presence of AlOOH particles on biochar surface according to scanning electron microscope (SEM) studies. The Langmuir maximum capacity best describes phosphate adsorption isotherm data to be around 135 mg/g. This makes the biochar/AlOOH nanocomposite a very competitive and efficient adsorbent that can be used in the recovery of phosphate from polluted water.

Jung et al. [41] used a dried microalga as a feedstock to prepare a Mg-Alassembled biochar. The biochar was prepared using an electro-assisted modification method by dipping the microalgae in MgCl2 solution with MgCl2 acting as an electrolyte. The solution pH was adjusted to 3 using NaOH solutions and 0.5 M H2SO4, and a current density was applied to the solid sample that was pyrolyzed at 600°C for 1 h at 5°C/min rate. This method reported the highest adsorption capacity of 887 mg/g according to the Langmuir-Freundlich model. Same authors [42] used the same electrochemical modification with changes in parameters such as using MgO nanocomposites instead of Mg-Al [41], resulting in a maximum adsorption capacity of 620 mg P/g.
